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89456

4,4′,4″,4″-（卟啉-5,10,15,20-四）四（苯磺酸）

Name: 4,4′,4″,4″-（卟啉-5,10,15,20-四）四（苯磺酸）
Brand: SIAL

for spectrophotometric det. of transition metals, ≥95.0%

别名:

内消旋(4-磺酸苯基)卟吩

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关于此项目

经验公式（希尔记法）:

C₄₄H₃₀N₄O₁₂S₄

化学文摘社编号:

35218-75-8

分子量:

934.99

UNSPSC Code:

23151817

NACRES:

NA.21

PubChem Substance ID:

329769738

MDL number:

MFCD00070632

Beilstein/REAXYS Number:

4227566

Assay:

≥95.0% (HPLC), ≥95.0%

Form:

powder

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属性

Quality Level

100

assay

≥95.0% (HPLC), ≥95.0%

form

powder

quality

for spectrophotometric det. of transition metals

technique(s)

UV/Vis spectroscopy: suitable

impurities

~9% water

SMILES string

OS(=O)(=O)c1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(cc4)S(O)(=O)=O)c5ccc([nH]5)c(-c6ccc(cc6)S(O)(=O)=O)c7ccc(n7)c(-c8ccc(cc8)S(O)(=O)=O)c9ccc2[nH]9

InChI

1S/C44H30N4O12S4/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57/h1-24,45,48H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

PBHVCRIXMXQXPD-LWQDQPMZSA-N

说明

Application

4,4′,4′′,4′′′-(卟啉-5,10,15,20-四基)四(苯磺酸)[四钠盐水合物，TPPS]已被用于制备Co–Al LDH/Fe(III)-TPPS薄膜修饰电极；用于证明Co(III)/Co(II)和铁(III)卟啉的可逆性氧化还原峰属性，该属性使其成为电子转移介质。

Packaging

无底玻璃瓶。内容物在插入式融锥内。

Analysis Note

最大吸收（甲醇溶液）：412-416nm

Other Notes

用于分光光度法测定超痕量过渡金属的试剂；用于毛细管区带电泳

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Kinetic effects of tartaric acid on the growth of chiral J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin.

Maria Angela Castriciano et al.

Chemical communications (Cambridge, England), 48(40), 4872-4874 (2012-04-14)

The kinetics of growth for chiral J-aggregates of H(4)TPPS(4) porphyrin have been investigated under different experimental conditions in the presence of tartaric acid. The observed rate constants and the anisotropy factor g show a defined dependence on the enantiomer used

Equilibrium, photophysical and photochemical examination of anionic lanthanum(III) mono- and bisporphyrins: the effects of the out-of-plane structure.

Zsolt Valicsek et al.

Dalton transactions (Cambridge, England : 2003), 41(42), 13120-13131 (2012-09-25)

Lanthanum(III) ions form kinetically labile complexes with the 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin anion (H(2)TSPP(4-)), the compositions and formation constants of which significantly depend on the presence of potential axial ligands (at 0.01 M). Deviating from the chloride ion, acetate coordinating to the metal

H. Ishii, H. Tsuchiai

Analytical Sciences, 3, 229-229 (1987)

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货号	GTIN
89456-100MG-F	04061832921167