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Merck
CN

90780

三丁胺

≥99.0% (GC), liquid, suitable for GC/GC, puriss. p.a.

别名:

Tri-n-butylamine

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关于此项目

线性分子式:
[CH3(CH2)3]3N
化学文摘社编号:
102-82-9
分子量:
185.35
NACRES:
NA.21
PubChem Substance ID:
57653405
UNSPSC Code:
12352100
EC Number:
203-058-7
MDL number:
MFCD00009431
Beilstein/REAXYS Number:
1698872
Assay:
≥99.0% (GC)
Technique(s):
GC/GC: suitable
Bp:
216 °C (lit.)
Vapor pressure:
0.3 mmHg ( 20 °C)
2.4 mmHg ( 55 °C)

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产品名称

三丁胺, puriss. p.a., ≥99.0% (GC)

InChI key

IMFACGCPASFAPR-UHFFFAOYSA-N

InChI

1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

SMILES string

CCCCN(CCCC)CCCC

vapor density

6.38 (vs air)

vapor pressure

0.3 mmHg ( 20 °C)
2.4 mmHg ( 55 °C)

grade

puriss. p.a.

assay

≥99.0% (GC)

form

liquid

autoignition temp.

410 °F

expl. lim.

6 %

technique(s)

GC/GC: suitable

impurities

≤0.2% water

refractive index

n20/D 1.428 (lit.)
n20/D 1.429

bp

216 °C (lit.)

mp

−70 °C (lit.)

density

0.778 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

functional group

amine

Quality Level

200

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相关类别

Application

三丁胺 ( n -Bu 3 n) 已被用于组成液相色谱串联质谱法 (LC-MS/MS) 分析的流动相。
可用于制备 Pd Cl,N 和 Pd OAc,N （钯纳米颗粒）。在 3-溴噻吩并[3,2- c ] 吡啶-4-(5 H ) 酮的合成过程中可作为添加剂使用。

General description

三丁胺是一种叔胺。据报道，它可以防止低碳钢在HCl溶液中被腐蚀。

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Skin Irrit. 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

剧毒化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN3337
BCCN2852
BCCL9961
BCCK5559
BCCB9883

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Boros EE and Kaldor I.
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Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins.
Le Bras J, et al.
New. J. Chem., 28(12), 1550-1553 (2004)
I E Flesch et al.
Infection and immunity, 56(6), 1464-1469 (1988-06-01)
Bone marrow-derived murine macrophages are able to inhibit the growth of Mycobacterium bovis and of some strains of M. tuberculosis after stimulation with either recombinant gamma interferon (rIFN-gamma) or lymphokines from antigen-specific T-cell clones. To elucidate the mechanism(s) involved in
A Helenius et al.
The Journal of general virology, 58 Pt 1, 47-61 (1982-01-01)
The effect of five lysosomotropic weak bases (chloroquine, amantadine, tributylamine, methylamine and NH4C1) on Semliki Forest virus (SFV) infection has been studied in BHK-21 cells. When present at concentrations equal to or greater than 0.1, 0.5, 2, 15 and 15
Christopher J Jones et al.
Journal of chromatography. A, 1217(4), 479-488 (2009-12-17)
Reverse-phase ion-pair high performance liquid chromatography (RPIP-HPLC) and ultra-performance liquid chromatography (RPIP-UPLC) are increasingly popular chromatographic techniques for the separation of organic compounds. However, the fine details of the RPIP separation mechanism are still being debated. Many factors including type
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