92330
硼酸三甲酯
purum, ≥99.0% (GC)
别名:
三甲氧基硼烷, 硼酸甲酯
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关于此项目
线性分子式:
B(OCH3)3
化学文摘社编号:
分子量:
103.91
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-468-9
Beilstein/REAXYS Number:
1697939
MDL number:
产品名称
硼酸三甲酯, purum, ≥99.0% (GC)
grade
purum
InChI key
WRECIMRULFAWHA-UHFFFAOYSA-N
InChI
1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3
SMILES string
COB(OC)OC
vapor density
3.59 (vs air)
assay
≥99.0% (GC)
form
liquid
refractive index
n20/D 1.346 (lit.)
n20/D 1.358
bp
68-69 °C (lit.)
mp
−34 °C (lit.)
density
0.932 g/mL at 20 °C (lit.)
Quality Level
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Application
硼酸三甲酯(TMB)可用于：
- 合成以三苯胺为核、外围接四苯乙烯单元的发光分子。
- 合成硼烷氨和三烷基胺硼烷。
- 在硼烷二甲硫醚的存在下还原羧酸。
- 交联磷酸盐复合物。
- 作为化学气相沉积法合成氮化硼纳米管的硼源。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - STOT SE 1
target_organs
Eyes
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
12.2 °F - (own results)
flash_point_c
-11 °C - (own results)
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Thermal-heating CVD synthesis of BN nanotubes from trimethyl borate and nitrogen gas.
Lin FH, et al.
Materials Chemistry and Physics, 107(1), 115-121 (2008)
Changing the Behavior of Chromophores from Aggregation?Caused Quenching to Aggregation?Induced Emission: Development of Highly Efficient Light Emitters in the Solid State.
Yuan W Z, et al.
Advanced Materials, 22(19), 2159-2163 (2010)
Organic synthesis using borane-methyl sulfide. II. Reduction of aromatic carboxylic acids in the presence of trimethyl borate.
Lane CF, et al.
The Journal of Organic Chemistry, 39(20), 3052-3054 (1974)
R Meder et al.
Solid state nuclear magnetic resonance, 15(1), 69-72 (2000-07-21)
Boron-11 nuclear magnetic resonance imaging and spectroscopy have been used to characterise the nature and distribution of boron compounds after preservative treatment of radiata pine wood with trimethylborate (TMB). One day after treatment, 11B magnetic resonance imaging microscopy showed significant
Scott Gronert et al.
Journal of the American Society for Mass Spectrometry, 13(9), 1088-1098 (2002-09-27)
Using a quadrupole ion trap mass spectrometer, trimethyl borate was allowed to react with dihydrogen phosphate, deprotonated O-phosphoserine, and a set of hydrogen bonded complexes involving dihydrogen phosphate and neutral acids (phosphoric acid, acetic acid, serine, and O-phosphoserine). The reactions
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