92337
溴三甲基硅烷
purum, ≥97.0% (AT)
别名:
TMBS, 三甲基溴化硅, 三甲基溴硅烷
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关于此项目
线性分子式:
(CH3)3SiBr
化学文摘社编号:
分子量:
153.09
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-672-0
Beilstein/REAXYS Number:
1731135
MDL number:
产品名称
溴三甲基硅烷, purum, ≥97.0% (AT)
InChI key
IYYIVELXUANFED-UHFFFAOYSA-N
InChI
1S/C3H9BrSi/c1-5(2,3)4/h1-3H3
SMILES string
C[Si](C)(C)Br
grade
purum
assay
≥97.0% (AT)
form
liquid
contains
silver wool as stabilizer
refractive index
n20/D 1.424 (lit.)
n20/D 1.424
bp
79 °C (lit.)
density
1.16 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
三甲基溴硅烷可作为衍生化试剂，用于通过气相色谱技术测定细胞培养基中的烷化溶血磷脂。
General description
三甲基溴硅烷可与Cl3共同用于催化烯丙基三甲基硅烷对各种醇的直接烯丙基化。
Other Notes
强效甲硅烷基化试剂；用于醚的裂解；以及膦酸和磷酸烷基酯的平稳裂解
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
10.4 °F - closed cup
flash_point_c
-12 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
C. Flann et al.
Journal of the American Chemical Society, 109, 6097-6097 (1987)
Gas chromatographic determination of alkyl lysophospholipids after solid-phase extraction from cell culture media
Coene J, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 612(1), 21-26 (1993)
S. Hanessian et al.
Tetrahedron Letters, 25, 2515-2515 (1984)
J T Sparrow et al.
Peptide research, 9(5), 218-222 (1996-09-01)
The original trimethylsilyl bromide (TMSBr) method of peptide resin deprotection and cleavage has been modified for convenience and applicability to larger peptides. Equal amounts of a 66-residue test peptide resin were cleaved by the standard hydrogen fluoride (HF) procedure, the
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Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs
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