92718
1-(三甲基硅基)咪唑 - 吡啶混合物
derivatization grade (GC derivatization), LiChropur™
别名:
TMSI+吡啶, 甲硅烷基化混合物 VII
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关于此项目
化学文摘社编号:
UNSPSC Code:
23151816
eCl@ss:
39151701
PubChem Substance ID:
NACRES:
NA.22
MDL number:
grade
derivatization grade (GC derivatization)
Quality Segment
description
1:4 (v/v)
form
liquid
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Silylations
technique(s)
gas chromatography (GC): suitable
density
0.98 g/mL at 20 °C
storage temp.
2-8°C
SMILES string
c1ccncc1.C[Si](C)(C)n2ccnc2
InChI
1S/C6H12N2Si.C5H5N/c1-9(2,3)8-5-4-7-6-8;1-2-4-6-5-3-1/h4-6H,1-3H3;1-5H
InChI key
PFVKFOIOKNIZKY-UHFFFAOYSA-N
General description
1-（三甲基硅烷）咪唑-吡啶混合物用于湿态糖样品和类固醇中受阻羟基的衍生化，并且可以和氟化酰化试剂一起进行氨基酸的衍生化。对于中度受阻或反应缓慢的化合物，吡啶是一种特别有用的1-（三甲基硅烷）咪唑（TMSI）溶剂，因为在涉及有机氯硅烷的硅烷化反应中它可以作为HCl受体。
Application
更多信息请参见产品信息
Other Notes
用于在温和条件下硅烷化醇。它通常称为 Tri-Sil Z
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
62.6 °F - closed cup
flash_point_c
17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter