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Merck
CN

93000

三苯基氯甲烷

purum, ≥97.0% (HPLC), ≥97.0% (AT)

别名:

三苯基甲基氯, 氯三苯甲烷, 氯代三苯甲烷

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关于此项目

线性分子式:
(C6H5)3CCl
化学文摘社编号:
76-83-5
分子量:
278.78
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
329770191
EC Number:
200-986-4
Beilstein/REAXYS Number:
397363
MDL number:
MFCD00000813
Assay:
≥97.0% (AT), ≥97.0% (HPLC)
Form:
powder

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InChI key

JBWKIWSBJXDJDT-UHFFFAOYSA-N

InChI

1S/C19H15Cl/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

SMILES string

ClC(c1ccccc1)(c2ccccc2)c3ccccc3

grade

purum

assay

≥97.0% (AT), ≥97.0% (HPLC)

form

powder

ign. residue

≤0.2% (as SO4)

bp

230-235 °C/20 mmHg (lit.)

Quality Level

200

mp

109-113 °C

solubility

chloroform: 0.1 g/mL, clear

functional group

chloro, phenyl

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相关类别

Application

  • Organic Synthesis: Research on the synthesis of 1, 2, 4-triazine derivatives, exploring the condensation reactions of trityl chloride with various compounds (Majid et al., 2020).

Other Notes

用于三苯甲基化的试剂；对敏感化合物进行三苯甲基化和随后的去三苯甲基化的有效方法

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
WXBF3742V
WXBF2663V
BCCK8945
WXBF2119V
BCCK3781

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J S Davidson et al.
Biochimica et biophysica acta, 847(1), 1-7 (1985-10-30)
Intercellular junctional communication was measured using [14C]citrulline incorporation in co-cultures of argininosuccinate synthetase-deficient and argininosuccinate lyase-deficient human fibroblasts. Triphenylmethane, triphenylmethylchloride and tetraphenylboron inhibited communication at concentrations at least 12-fold lower than cytotoxic concentrations. This inhibition was of rapid onset and
Ryuichi Hasegawa et al.
Congenital anomalies, 45(4), 137-145 (2005-12-20)
To elucidate the comparative susceptibility of newborn rats to chemicals, newborn and young animals were administered six industrial chemicals by gavage from postnatal days (PND) 4 to 21, and for 28 days starting at 5-6 weeks of age respectively, under
R Hasegawa et al.
Regulatory toxicology and pharmacology : RTP, 47(3), 296-307 (2006-12-13)
We comprehensively re-analyzed the toxicity data for 18 industrial chemicals from repeated oral exposures in newborn and young rats, which were previously published. Two new toxicity endpoints specific to this comparative analysis were identified, the first, the presumed no observed
S J Harding et al.
Journal of peptide science : an official publication of the European Peptide Society, 5(8), 368-373 (1999-10-03)
A rational attempt to prepare FmocHis(piTrt)OH regiospecifically gave in fact the well-known tau-trityl isomer, and experiments with model systems indicate that the prospects for access to pi-trityl histidine derivatives, which would be of great value for the racemization-free synthesis of
K. Barlos et al.
The Journal of Organic Chemistry, 47, 1324-1324 (1982)
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