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Merck
CN

932175

Potassium hexachloroplatinate(IV) CHEMBEADS

solid

别名:

Dipotassium hexachloroplatinate, Dipotassium platinum hexachloride, Platinic potassium chloride, Platinum potassium chloride, Potassium chloroplatinate, Potassium platinum(IV) chloride, Potassium platinum(IV) hexachloride

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关于此项目

经验公式（希尔记法）:
K2PtCl6
化学文摘社编号:
16921-30-5
分子量:
485.99
UNSPSC Code:
12352302
NACRES:
NA.22

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产品名称

Potassium hexachloroplatinate(IV) CHEMBEADS,

SMILES string

[K][K].Cl[Pt](Cl)(Cl)(Cl)(Cl)Cl

InChI

1S/6ClH.2K.Pt/h6*1H;;;/q;;;;;;2*+1;+4/p-6

InChI key

DPAIVKJGTXERIM-UHFFFAOYSA-H

Quality Level

100

product line

ChemBeads

form

solid

storage temp.

2-8°C

相关类别

Application

Potassium hexachloroplatinate (K2PtCl6) can be used to synthesize:
  • K2PtCl6-PEG/SiO2 complex catalytic system for vapor-phase hydrosilylation reaction.
  • Pt-decorated nickel pyrophosphate ß-Ni2P2O7/Pt and nickel phosphate Ni3(PO4)2/Pt catalysts for the hydrogen evolution reaction (HER) by water splitting.
  • Polypyrrole-platinum complex sphere catalyst for the decomposition of hydrogen peroxide to form oxygen.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

Product is also available as neat precatalyst (206067)

General description

Potassium hexachloroplatinate (K2PtCl6) is the inorganic compound that is commonly used as a platinum (Pt) precursor for the preparation of platinum-based compounds.

Other Notes

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 1

flash_point_f

does not flash

flash_point_c

does not flash

法规信息

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分析证书(COA)

Lot/Batch Number
MKCS9326

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Versatile Methods to Dispense Submilligram Quantities of Solids Using Chemical-Coated Beads for High-Throughput Experimentation
Martin, et al.
Organic Process Research & Development, 2, 1900?1907-1900?1907 (2019)
Noah P Tu et al.
Angewandte Chemie (International ed. in English), 58(24), 7987-7991 (2019-03-21)
Technologies that enable rapid screening of diverse reaction conditions are of critical importance to methodology development and reaction optimization, especially when molecules of high complexity and scarcity are involved. The lack of a general solid dispensing method for chemical reagents
Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of

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