93510
(S)-Trolox 甲醚
derivatization grade (chiral), LiChropur™, ≥98.0%
别名:
(S)-6-甲氧基-2,5,7,8-四甲基色烷-2-羧酸
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关于此项目
经验公式（希尔记法）:
C15H20O4
化学文摘社编号:
分子量:
264.32
UNSPSC Code:
41115710
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5481541
Assay:
≥98.0% (sum of enantiomers, HPLC), ≥98.0%
Form:
powder
InChI
1S/C15H20O4/c1-8-9(2)13-11(10(3)12(8)18-5)6-7-15(4,19-13)14(16)17/h6-7H2,1-5H3,(H,16,17)/t15-/m0/s1
SMILES string
COc1c(C)c(C)c2O[C@@](C)(CCc2c1C)C(O)=O
InChI key
MNBMVDGIDVXTOF-HNNXBMFYSA-N
grade
derivatization grade (chiral)
assay
≥98.0% (sum of enantiomers, HPLC), ≥98.0%
form
powder
optical activity
[α]20/D −69±2°, c = 1% in ethanol
optical purity
enantiomeric ratio: ≥99.5:0.5 (HPLC)
quality
LiChropur™
technique(s)
HPLC: suitable
mp
143-145 °C
Quality Level
General description
(S)-Trolox 甲醚是一种手性衍生剂，用于将对映异构体衍生为非对映异构体。
Application
(S)-Trolox 甲醚可用作手性衍生试剂，用于以下用途：
- 通过毛细管气相色谱（GC）和超临界流体色谱（SFC）分析手性醇
- 使用气相色谱（GC）、超临界流体色谱（SFC）和亚临界流体色谱技术对几种苯二氮卓类药物进行对映体分离
Packaging
无底玻璃瓶。内含物装在锥底内插管中。
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Direct and indirect approaches to enantiomeric separation of benzodiazepines using micro column techniques
Almquist RS, et al.
Journal of Chromatography A, 679(1), 139-146 (1994)
W. Walther et al.
J. Microcol. Sep., 4, 45-45 (1992)
Design and development of chiral reagents for the chromatographic ee determination of chiral alcohols
Walther W and Netscher T
Chirality, 8(5), 397-401 (1996)
W. Walther et al.
Chimia, 45, 121-121 (1991)
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