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Merck
CN

938750

Sigma-Aldrich

GPhos ChemBeads

solid

别名:

(3-(tert-Butoxy)-2′,6′-diisopropyl-6-methoxy-[1,1′-biphenyl]-2-yl)dicyclohexylphosphane ChemBeads

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About This Item

经验公式(希尔记法):
C35H53O2P
CAS Number:
分子量:
536.77
MDL编号:
UNSPSC代码:
12352100
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Product Name

GPhos ChemBeads,

表单

solid

质量水平

组成

loading of catalyst, 4-6 wt. %

反应适用性

reaction type: Cross Couplings
reagent type: catalyst
reagent type: ligand

mp

230-233 °C

官能团

phosphine

SMILES字符串

CC(C(C=CC=C1C(C)C)=C1C2=C(OC)C=CC(OC(C)(C)C)=C2P(C3CCCCC3)C4CCCCC4)C

InChI

1S/C35H53O2P/c1-24(2)28-20-15-21-29(25(3)4)32(28)33-30(36-8)22-23-31(37-35(5,6)7)34(33)38(26-16-11-9-12-17-26)27-18-13-10-14-19-27/h15,20-27H,9-14,16-19H2,1-8H3

InChI key

JKLUIDIKASJZCK-UHFFFAOYSA-N

相关类别

一般描述

GPhos is a Buchwald-type ligand used in various cross-coupling reactions.

应用

GPhos is a dialkylbiaryl monophosphine ligand developed by the Buchwald group for aryl amination reactions. The GPhos Pd oxidative addition complex (OAC) enables room temperature C-N couplings with complex substrates at higher efficiency than previously developed ligands.

Learn more about Buchwald Phosphine Ligands

For general uses, product is also available in powdered form (918008)

特点和优势

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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