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Merck
CN

939013

Copper(I) iodide ChemBeads

solid

别名:

Cuprous iodide

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关于此项目

经验公式(希尔记法):
CuI
化学文摘社编号:
分子量:
190.45
MDL number:
UNSPSC Code:
12352100
NACRES:
NA.21
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产品名称

Copper(I) iodide ChemBeads,

SMILES string

[Cu+].[I-]

InChI

1S/Cu.HI/h;1H/q+1;/p-1

InChI key

LSXDOTMGLUJQCM-UHFFFAOYSA-M

description

Inorganic Salt

Quality Level

product line

ChemBeads

form

solid

composition

loading of base, 14-16 wt. %

reaction suitability

reagent type: catalyst
core: copper
reaction type: click chemistry

Features and Benefits

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

General description

Copper(I) iodide ChemBeads are the inorganic Copper(I) iodide salt coated on glass beads.

Application

Copper Iodide has many applications in organic reactions, including living radical polymerizations (Atom Transfer Radical Polymerization or ATRP) and cross coupling reactions. CuI has also been used in the fabrication of solar cells, photoluminescents, and nanocrystal synthesis.
Optimal catalyst for stereospecific and regioselective reaction of silacyclopropanes with carbonyl compounds.
For general uses, product is also available in powdered form 205540

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Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Oral

target_organs

Thyroid

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Noah P Tu et al.
Angewandte Chemie (International ed. in English), 58(24), 7987-7991 (2019-03-21)
Technologies that enable rapid screening of diverse reaction conditions are of critical importance to methodology development and reaction optimization, especially when molecules of high complexity and scarcity are involved. The lack of a general solid dispensing method for chemical reagents
Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of

商品

ChemBeads, catalyst-coated glass beads, dispense solid chemical reagents for nanomole-scale high-throughput reaction screening.

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