C102180
环己酮
99.8%, liquid, suitable for synthesis, ReagentPlus®
别名:
pimelic ketone
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关于此项目
线性分子式:
C6H10(=O)
化学文摘社编号:
分子量:
98.14
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-631-1
MDL number:
Beilstein/REAXYS Number:
385735
Assay:
99.8%
Bp:
155 °C (lit.)
Vapor pressure:
3.4 mmHg ( 20 °C)
产品名称
环己酮, ReagentPlus®, 99.8%
InChI key
JHIVVAPYMSGYDF-UHFFFAOYSA-N
InChI
1S/C6H10O/c7-6-4-2-1-3-5-6/h1-5H2
SMILES string
O=C1CCCCC1
vapor density
3.4 (vs air)
vapor pressure
3.4 mmHg ( 20 °C)
product line
ReagentPlus®
assay
99.8%
form
liquid
autoignition temp.
788 °F
expl. lim.
1.1 %, 100 °F, 9.4 %
dilution
(for general lab use)
Quality Level
pH
~7 (20 °C, 70 g/L)
bp
155 °C (lit.)
mp
−47 °C (lit.)
density
0.947 g/mL at 25 °C (lit.)
functional group
ketone
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General description
环己酮是一种环酮，可通过环己烷氧化或苯酚氢化制得。环己酮是生产己内酰胺、己二酸和尼龙的重要原料。可作为溶剂用于杀虫剂、木材染料、漆和脱漆剂、去渍剂、纤维素、天然和合成类树脂和漆。
Application
环己酮可作为反应剂合成：
- 通过还原氨化生成仲胺。
- 己二酸。
- 四取代炔丙胺类。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
111.2 °F - closed cup
flash_point_c
44 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Kinetics of oxidation of cyclohexanone in a jet-stirred reactor: Experimental and modeling.
Serinyel Z, et al.
Proceedings of the Combustion Institute, 35(1), 507-514 (2015)
Selective transfer hydrogenation of phenol to cyclohexanone on supported palladium catalyst using potassium formate as hydrogen source under open atmosphere.
Patil RD and Sasson Y.
Applied Catalysis A: General, 499, 227-231 (2015)
Supported zirconium-based continuous-flow microreactor for effective Meerwein-Ponndorf-Verley reduction of cyclohexanone.
Koreniuk A, et al.
Catalysis Communications, 64, 48-51 (2015)
Green and Sustainable Heterogeneous Organo-Catalyst for Asymmetric Aldol Reactions.
Sadiq M, et al.
Modern Research in Catalysis, 4(2), 43-43 (2015)
Synthesis of tetrasubstituted propargylamines from cyclohexanone by solvent-free copper (II) catalysis.
Palchak ZL, et al.
Green Chemistry, 17(3), 1802-1810 (2015)
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