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Merck
CN

CN205680

碳负载钯催化剂

extent of labeling: 5 wt. % loading (dry basis), matrix activated carbon support, powder, matrix wet support

别名:

Pd/C

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关于此项目

线性分子式:
Pd
分子量:
106.42
UNSPSC Code:
12141733
PubChem Substance ID:
MDL number:
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InChI

1S/Pd

SMILES string

[Pd]

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

form

powder

reaction suitability

reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
core: palladium
reaction type: Heck Reaction, reagent type: catalyst
core: palladium
reaction type: Hiyama Coupling, reagent type: catalyst
core: palladium
reaction type: Negishi Coupling, reagent type: catalyst
core: palladium
reaction type: Sonogashira Coupling, reagent type: catalyst
core: palladium
reaction type: Stille Coupling, reagent type: catalyst
core: palladium
reaction type: Suzuki-Miyaura Coupling

extent of labeling

5 wt. % loading (dry basis)

matrix

activated carbon support, wet support

Quality Level

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

催化以下反应:
  • Stille反应
  • 氢化反应
  • Suzuki-Miyaura交叉偶联反应和Heck-Mizoroki反应
  • 脱氧反应
  • 氧化反应
  • 偶联反应
Catalyst for:

  • Stille reaction
  • Hydrogenation reactions
  • Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
  • Deoxygenation
  • Oxidation reactions
  • Coupling reactions

Palladium on carbon (Pd/C) (5 wt. % loading (dry basis), matrix activated carbon support) can be used for a variety of applications, such as:

  • a catalyst for hydrodechlorination of dichlorodifluoromethane (CCl2F2), which is a known greenhouse gas
  • a catalyst for Heck reactions of aryl halides in ionic liquids
  • an anode catalyst for the fabrication of direct formic acid fuel cells (DFAFC)
  • a cost-effective electrocatalyst for the oxidation of methanol
  • in the catalytic hydrogenation of chemical hydrides for the production of hydrogen
  • a catalyst in Suzuki-Mayaura reaction
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride
Patel N, et al.
International Journal of Hydrogen Energy, 33(1), 287-292 (2008)
Characterisation of the deactivation of platinum and palladium supported on activated carbon used as hydrodechlorination catalysts
Ordonez S, et al.
Applied Catalysis. B, Environmental, 31(2), 113-122 (2001)
Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid
Hagiwara H, et al.
Tetrahedron Letters, 42(26), 4349-4351 (2001)
Performance characterization of Pd/C nanocatalyst for direct formic acid fuel cells
Ha S, et al.
Journal of Power Sources, 144(1), 28-34 (2005)
Svilen P Simeonov et al.
ChemSusChem, 12(12), 2748-2754 (2019-05-06)
A new scalable synthesis of pentane-1,2,5-triol from the furanics platform has been developed. Excellent yields of up to 92 % are obtained under flow conditions by using readily available catalysts from the existing pool. The strategy exploits the highly functionalized Achmatowicz

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