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经验公式(希尔记法):
C6H10Cl2Pd2
化学文摘社编号:
分子量:
365.89
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
Beilstein/REAXYS Number:
4124623
MDL number:
Quality Segment
reaction suitability
reagent type: catalyst
core: palladium
reaction type: C-H Activation, reagent type: catalyst
core: palladium
reaction type: Cross Couplings
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
SMILES string
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
InChI key
TWKVUTXHANJYGH-UHFFFAOYSA-L
General description
Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.[] We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. These highly active catalyst complexes are used in Suzuki-Miyaura, Buchwald-Hartwig, and Heck reactions, enabling efficient C-C and C-N bond formation in sustainable synthesis, offering a greener, potentially more sustainable option for industrial chemical processes. Click here for more information.
Application
Features and Benefits
Application Guide for Palladium Catalyzed Cross-Coupling Reactions Allylpalladium(II) chloride dimer has been employed for the following studies: Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.[] Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.[] Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.[] As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M. On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
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signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
存储类别
11 - Combustible Solids
