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Merck
CN

CN222380

氯化烯丙基钯(II)二聚体

greener alternative

更环保的选择

别名:

\ [氯化钯(C3H5)] 2

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关于此项目

经验公式(希尔记法):
C6H10Cl2Pd2
化学文摘社编号:
分子量:
365.89
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
Beilstein/REAXYS Number:
4124623
MDL number:
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Quality Segment

reaction suitability

reagent type: catalyst
core: palladium
reaction type: C-H Activation, reagent type: catalyst
core: palladium
reaction type: Cross Couplings

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

SMILES string

Cl[Pd]CC=C.Cl[Pd]CC=C

InChI

1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2

InChI key

TWKVUTXHANJYGH-UHFFFAOYSA-L

General description

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.[] We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. These highly active catalyst complexes are used in Suzuki-Miyaura, Buchwald-Hartwig, and Heck reactions, enabling efficient C-C and C-N bond formation in sustainable synthesis, offering a greener, potentially more sustainable option for industrial chemical processes. Click here for more information.

Features and Benefits

Application Guide for Palladium Catalyzed Cross-Coupling Reactions Allylpalladium(II) chloride dimer has been employed for the following studies: Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.[] Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.[] Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.[] As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M. On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors


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Warning

hcodes

Hazard Classifications

Skin Irrit. 2

存储类别

11 - Combustible Solids



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