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Merck
CN

CN676578

双(三叔丁基膦)钯(0)

solid, 98%

别名:

Pd(t-Bu3P)2

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关于此项目

经验公式（希尔记法）:
C24H54P2Pd
化学文摘社编号:
53199-31-8
分子量:
511.05
NACRES:
NA.22
PubChem Substance ID:
24884857
UNSPSC Code:
12161600
MDL number:
MFCD03094580

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产品名称

双(三叔丁基膦)钯(0), solid, 98%

InChI

1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;

SMILES string

[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C

InChI key

MXQOYLRVSVOCQT-UHFFFAOYSA-N

assay

98%

form

solid

quality

200

reaction suitability

reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: catalyst
core: palladium
reaction type: Cross Couplings
reagent type: catalyst
core: palladium
reaction type: Heck Reaction
reagent type: catalyst
core: palladium
reaction type: Hiyama Coupling
reagent type: catalyst
core: palladium
reaction type: Negishi Coupling
reagent type: catalyst
core: palladium
reaction type: Sonogashira Coupling
reagent type: catalyst
core: palladium
reaction type: Stille Coupling
reagent type: catalyst
core: palladium
reaction type: Suzuki-Miyaura Coupling

mp

258-272 °C

Quality Level

200

Application

1. Catalyst for Suzuki coupling on a multisubstituted sp3-carbon[] (eq. 1) 2. Catalyst for Stille coupling reaction of aryl chlorides[] (eq. 2) 3. Catalyst for Negishi coupling reaction[3] (eq. 3) 4. Catalyst for Heck coupling to form tetrasubstituted olefins[] (eq. 4) 5. Catalyst for Buchwald-Hartwig amination of aryl halide[] (eq. 5) 6. Catalyst for carbonylation of aryl halides with carbamoylsilanes[] (eq. 6) 7. Catalyst for greener Heck reaction in TPGS-750-M. On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here. (https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201302020)

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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