T28002
茴香硫醚
ReagentPlus®, ≥99%
别名:
甲基苯基硫醚
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线性分子式:
C6H5SCH3
化学文摘社编号:
分子量:
124.20
Beilstein:
1904179
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21
质量水平
产品线
ReagentPlus®
方案
≥99%
折射率
n20/D 1.587 (lit.)
沸点
188 °C (lit.)
mp
−15 °C (lit.)
密度
1.057 g/mL at 20 °C (lit.)
官能团
thioether
SMILES字符串
CSc1ccccc1
InChI
1S/C7H8S/c1-8-7-5-3-2-4-6-7/h2-6H,1H3
InChI key
HNKJADCVZUBCPG-UHFFFAOYSA-N
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应用
硫代苯甲醚可用于通过氧化合成甲基苯基亚砜。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险分类
Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1B
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
163.4 °F - closed cup
闪点(°C)
73 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Mild and selective oxidation of sulfur compounds in trifluoroethanol: diphenyl disulfide and methyl phenyl sulfoxide.
Ravikumar KS, et al.
Organic Syntheses, 184-189 (2003)
Methyl phenyl sulfoxide.
Johnson CR & Keiser JE.
Organic Syntheses, 78-78 (1966)
Jun-Long Zhang et al.
Chemical communications (Cambridge, England), (14)(14), 1665-1667 (2008-03-28)
We demonstrate that incorporation of MnSalen into a protein scaffold enhances the chemoselectivity in sulfoxidation of thioanisole and find that both the polarity and hydrogen bonding of the protein scaffold play an important role in tuning the chemoselectivity.
Viktor Mojr et al.
Chemical communications (Cambridge, England), 46(40), 7599-7601 (2010-09-14)
β-Cyclodextrin-flavin conjugates are highly efficient catalysts for the sulfoxidation of methyl phenyl sulfides with hydrogen peroxide in neat aqueous media operating at loadings down to 0.2 mol% and allowing for enantioselectivities up to 80% ee.
Chun Zhu et al.
Physical chemistry chemical physics : PCCP, 14(37), 12800-12806 (2012-08-10)
The electronic and structural features of (oxo)manganese(V) corroles and their catalyzed oxygen atom transfers to thioanisole in different spin states have been investigated by the B3LYP functional calculations. Calculations show that these corrole-based oxidants and their complexes with thioanisole generally
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