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Merck
CN

10029

硫酸汞(II)

puriss., ≥98%

别名:

硫酸汞

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关于此项目

线性分子式:
HgSO4
化学文摘社编号:
分子量:
296.65
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.55
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等级

puriss.

质量水平

方案

≥98%

表单

powder or crystals

灼烧残渣(使用HCOOH还原后)

≤0.1% (as SO4)

痕量阴离子

chloride (Cl-): ≤50 mg/kg

痕量阳离子

Fe: ≤50 mg/kg

SMILES字符串

[Hg++].[O-]S([O-])(=O)=O

InChI

1S/Hg.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2

InChI key

DOBUSJIVSSJEDA-UHFFFAOYSA-L

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应用

Mercury(II) sulfate can be used as a catalyst in the presence of sulfuric acid (H2SO4) for the:
  • Direct oxidation of methane to methanol.
  • Hydration of alkynes to the corresponding carbonyl compounds.
  • Conversion of alkyl protected glycals into their corresponding α,β-unsaturated enals (Perlin aldehydes).

警示用语:

Danger

危险分类

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

靶器官

Kidney

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Laurie F Caslake et al.
Applied and environmental microbiology, 70(2), 1145-1150 (2004-02-10)
Contaminated water causes an estimated 6 to 60 billion cases of gastrointestinal illness annually. The majority of these cases occur in rural areas of developing nations where the water supply remains polluted and adequate sanitation is unavailable. A portable, low-cost
Tariq SA and Hill JO.
J. Therm. Anal., 212, 277-281 (1981)
Direct oxidation of methane to methanol by mercuric sulfate catalyst.
Gang X, et al.
J. Catal., 196(2), 287-292 (2000)
Catalysis by mercuric ion of reactions of glycals with water.
Gonzalez F, et al.
Carbohydrate Research, 42(2), 267-274 (1975)
Ai-hua Liang et al.
Zhongguo Zhong yao za zhi = Zhongguo zhongyao zazhi = China journal of Chinese materia medica, 30(4), 249-252 (2005-02-24)
Traditional Chinese medicine (TCM) experienced a gradual course in recognition of the toxicity of Cinnabaris from "nontoxic" to "toxic". The ancient doctors of TCM understood both the toxic property and the regularity of increasing toxicity of Cinnabaris. In long-term clinical

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