12849
硫酸铜 五水合物
puriss., suitable for, meets analytical specification of Ph. Eur., BP, USP,FCC
别名:
Cupric sulfate 五水合物, 硫酸，铜（II）盐（1：1）五水合物
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关于此项目
线性分子式:
CuSO4 · 5H2O
化学文摘社编号:
分子量:
249.69
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-847-6
MDL number:
Assay:
98.5-100.5% (USP)
Form:
crystals
InChI key
JZCCFEFSEZPSOG-UHFFFAOYSA-L
InChI
1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
SMILES string
O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O
vapor pressure
7.3 mmHg ( 25 °C)
grade
puriss.
assay
98.5-100.5% (USP)
form
crystals
quality
meets analytical specification of Ph. Eur., BP, USP,FCC
Quality Level
loss
35.0-36.5% loss on drying, 250 °C
pH
3.5-4.5 (20 °C, 50 g/L)
mp
110 °C (dec.) (lit.)
anion traces
chloride (Cl-): ≤100 mg/kg
cation traces
As: ≤5 mg/kg, Ca: ≤50 mg/kg, Fe: ≤30 mg/kg, K: ≤100 mg/kg, Mg: ≤50 mg/kg, Na: ≤200 mg/kg, Ni: ≤50 mg/kg, Pb: 4 ppm
suitability
passes test for appearance of solution, suitable for
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General description
五水硫酸铜（II）（CuSO4·5H2O，胆矾）是一种水合铜（II）盐。它能与三脚架配体发生水热反应，产生金属-有机骨架（MOF）。CuSO4·5H2O 与金属铜能够一起催化不同配体臂官能化偶氮酰胺的合成。当加热到560℃以上后，它会分解成CuO。
Application
五水硫酸铜（II）可用于以下研究：
- 在无溶剂条件下作为醇和酚乙酰化的催化剂。
- 制备用于Cu-Zn-Sn前体电沉积的电解质，它是制备Cu2ZnSnS4 (CZTS)薄膜所必需的。
- 作为乙醇的脱水反应的催化剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
flash_point_f
Not applicable
flash_point_c
Not applicable
存储类别
11 - Combustible Solids
Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
Damijana Urankar et al.
Journal of combinatorial chemistry, 10(6), 981-985 (2008-10-17)
Azoamides, previously established as bioactive intracellular GSH-depleting agents, were decorated with a terminal alkyne moiety to 4 and then were transformed, by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC), into different ligand-arm functionalized azoamides 6. Azides 5 having ligand-arms amenable for binding to
Preparation of Cu2ZnSnS4 thin films by sulfurization of co-electroplated Cu-Zn-Sn precursors.
Araki H, et al.
Physica Status Solidi, 6(5), 1266-1268 (2009)
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