12852
硫酸铜
puriss., meets analytical specification of Ph. Eur., BP, USP, anhydrous, 99-100.5% (based on anhydrous substance)
别名:
Cupric sulfate
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关于此项目
线性分子式:
CuSO4
化学文摘社编号:
分子量:
159.61
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-847-6
MDL number:
Assay:
99-100.5% (based on anhydrous substance)
Form:
solid
InChI key
ARUVKPQLZAKDPS-UHFFFAOYSA-L
InChI
1S/Cu.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2
SMILES string
[Cu++].[O-]S([O-])(=O)=O
vapor pressure
7.3 mmHg ( 25 °C)
grade
puriss.
assay
99-100.5% (based on anhydrous substance)
form
solid
quality
meets analytical specification of Ph. Eur., BP, USP
impurities
residual solvents, complies
loss
≤1% loss on drying, 250 °C
pH
3.5-4.5 (20 °C, 50 g/L)
mp
200 °C (dec.) (lit.)
density
3.603 g/mL at 25 °C (lit.)
anion traces
chloride (Cl-): ≤100 mg/kg
cation traces
Ca: ≤50 mg/kg, Fe: ≤30 mg/kg, K: ≤100 mg/kg, Mg: ≤100 mg/kg, Na: ≤200 mg/kg, Ni: ≤50 mg/kg, Pb: ≤80 mg/kg
Quality Level
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General description
Copper(II) sulfate acts as a redox catalyst along with potassium permanganate for the oxidation of alcohols. On heating above 560°C, it decomposes to CuO.5
It can find applications in agriculture as a nutrient for plants. It can also serve as a precursor in the production of foliar bactericides and fungicides.
It can find applications in agriculture as a nutrient for plants. It can also serve as a precursor in the production of foliar bactericides and fungicides.
Application
Copper(II) sulfate may be employed for the following studies:
- As a catalyst for the acetylation of alcohols and phenols under solvent-free conditions.
- To compose the electrolyte for the electrodeposition of Cu-Zn-Sn precursors, required for the preparation of Cu2ZnSnS4 (CZTS) thin films.
- As a Lewis acid catalyst for the dehydration of alcohols.5
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Author - Richardson W.H
Handbook of Copper Compounds and Applications (1997)
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
William T Triplett et al.
Magnetic resonance in medicine, 72(1), 8-19 (2013-09-06)
The relationship between fat fractions (FFs) determined based on multiple TE, unipolar gradient echo images and (1) H magnetic resonance spectroscopy (MRS) was evaluated using different models for fat-water decomposition, signal-to-noise ratios, and excitation flip angles. A combination of single-voxel
Preparation of Cu2ZnSnS4 thin films by sulfurization of co-electroplated Cu-Zn-Sn precursors.
Araki H, et al.
Physica Status Solidi, 6(5), 1266-1268 (2009)
Hung T Vu et al.
Environmental toxicology and chemistry, 33(4), 791-797 (2013-12-10)
The assumption of the individual effective dose is the basis for the probit method used for analyzing dose or concentration-response data. According to this assumption, each individual has a uniquely innate tolerance expressed as the individual effective dose (IED) or
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