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161527

硫氢化钠 水合物

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关于此项目

线性分子式:
NaSH·xH2O
化学文摘社编号:
分子量:
56.06 (anhydrous basis)
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
chips, flakes
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Quality Level

form

chips, flakes

concentration

≥60% (by Na2S2O3, titration)

mp

52-54 °C (lit.)

SMILES string

[Na]S.[H]O[H]

InChI

1S/Na.H2O.H2S/h;2*1H2/q+1;;/p-1

InChI key

ZNKXTIAQRUWLRL-UHFFFAOYSA-M

General description

氢硫化钠水合物是钠的水合无机盐。它参与合成(E)-2-氰基-2-(噻唑烷-2-亚基)硫代乙酰胺。

Application

它可以用作硫亲核试剂以诱导α,β-二氯乙烯基酮中的CS键形成,以形成5-至8-元环状硫醚。
氢硫化钠水合物可用于以下合成:
  • 苯并噻唑
  • 4-甲氧基苯并硫代酰胺
  • 2-(4-甲氧基苯基)咪唑啉
  • 7-氯-4′-甲氧基硫黄酮


signalword

Danger

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

flash_point_f

194.0 °F - closed cup

flash_point_c

90 °C - closed cup

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B

法规信息

监管及禁止进口产品

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Mehdi Bakavoli et al.
Molecules (Basel, Switzerland), 14(12), 4849-4857 (2009-12-25)
Cyclocondensation of 2-[bis(methylthio)methylene]malononitrile (1) and cysteamine (2) afforded 2-(thiazolidin-2-ylidene)malononitrile (3). This compound on treatment with NaSH gave the corresponding thioamide derivative 4a in a regioselective manner on the basis of its single crystal X-ray diffraction analysis. Reaction of this compound
Bruna M Santos et al.
Acta physiologica (Oxford, England), 228(3), e13373-e13373 (2019-09-05)
Whereas some patients have important changes in body core temperature (Tb) during systemic inflammation, others maintain a normal Tb, which is intrinsically associated to immune paralysis. One classical model to study immune paralysis is the use of repeated administration of
Synthesis of Benzothiazoles through Copper-Catalyzed One-Pot Three-Component Reactions with Use of Sodium Hydrosulfide as a Sulfur Surrogate.
Park N, et al.
European Journal of Organic Chemistry, 10, 1984-1993 (2012)



全球贸易项目编号

货号GTIN
161527-100G04061838746450
161527-3KG04061838746474
161527-5G04061838746481
161527-1KG04061838746467