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Merck
CN

184497

1,3-二氧戊环

ReagentPlus®, contains ~75 ppm BHT as inhibitor, 99%

别名:

乙二醇亚甲基醚, 乙二醇缩甲醛

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关于此项目

经验公式(希尔记法):
C3H6O2
化学文摘社编号:
分子量:
74.08
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
EC Number:
211-463-5
Beilstein/REAXYS Number:
102453
MDL number:
Assay:
99%
Bp:
75-76 °C/1.013 hPa
Vapor pressure:
70 mmHg ( 20 °C)
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InChI key

WNXJIVFYUVYPPR-UHFFFAOYSA-N

InChI

1S/C3H6O2/c1-2-5-3-4-1/h1-3H2

SMILES string

C1COCO1

vapor density

2.6 (vs air)

vapor pressure

70 mmHg ( 20 °C)

product line

ReagentPlus®

assay

99%

form

liquid

autoignition temp.

525 °F

contains

~75 ppm BHT as inhibitor

expl. lim.

2.1-20.5 %

dilution

(for general lab use)

Quality Level

bp

75-76 °C/1.013 hPa

mp

−95 °C (lit.)

density

1.06 g/mL at 25 °C (lit.)

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General description

1,3-二氧杂环戊烷 (DOXL) 是一种环醚。它是一种绿色溶剂。它与 C 60 反应得到环氧化物和 1,3-二氧杂环戊烷衍生物。据报告,反应是通过双自由基机理进行的。以四(乙二醇)二甲醚 (TEGDME) 和 DOXL 组成二元电解质,用于锂硫电池。它在非水氧化还原流电池系统中作为溶剂的功效已被测试。

Application

1,3-二氧戊环可用于制造电池和电容器。 可作为制备锂硫电池电解液的助溶剂之一。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

26.6 °F - closed cup

flash_point_c

-3 °C - closed cup

法规信息

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Binary electrolyte based on tetra (ethylene glycol) dimethyl ether and 1, 3-dioxolane for lithium-sulfur battery.
Chang DR, et al.
Journal of Power Sources, 112(2), 452-460 (2002)
Hideki Miyatake-Ondozabal et al.
Organic letters, 12(23), 5573-5575 (2010-11-12)
The biomimetic total synthesis of LL-Z1640-2 (3) is reported without the use of phenol protection. The aromatic unit was constructed via the transannular aromatization of macrocyclic triketo-ester 2, which in turn was synthesized by macrolactonization using an intramolecular trapping of
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