等级
ACS reagent
质量水平
蒸汽压
1 mmHg ( 136.5 °C)
表单
powder
反应适用性
reagent type: catalyst
core: mercury
杂质
≤0.05% insol. CH3OH
还原残留物
≤0.02%
颜色
white to very faintly yellow
沸点
322 °C (lit.)
mp
236 °C (lit.)
痕量阴离子
chloride (Cl-): ≤0.25%
SMILES字符串
Br[Hg]Br
InChI
1S/2BrH.Hg/h2*1H;/q;;+2/p-2
InChI key
NGYIMTKLQULBOO-UHFFFAOYSA-L
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一般描述
Mercury(II) bromide (HgBr2) affords 1:1 adducts on reaction with N,N,N′,N′- tetramethyl-o-phenylenediamine. Single-crystal X-ray diffraction studies of these adducts have been reported. It forms complexes by reacting with 3,12-dimethylbenzo[a]quinoxalino[2,3-c]phenazine ligand.
应用
Mercury(II) bromide (HgBr2) may be used in the preparation of mononuclear [Hg(L1)Br2] and 1D polymer [Hg2(L2)Br4]n [L1 = (N,N-diethyl,N′-(pyridin-2-yl)formylidene)ethane-1,2-diamine and L2 = (N,N-diethyl,N′-(pyridin-2-yl)benzylidene)ethane-1,2-diamine]. It may also be used as a promoter in the glycoslyation reaction of alcohols.
警示用语:
Danger
危险分类
Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
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