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Merck
CN

205222

氰化钠

ACS reagent, ≥95.0%

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关于此项目

线性分子式:
NaCN
化学文摘社编号:
分子量:
49.01
UNSPSC Code:
12352300
NACRES:
NB.24
PubChem Substance ID:
EC Number:
205-599-4
Beilstein/REAXYS Number:
3587243
MDL number:
Assay:
≥95.0%
Grade:
ACS reagent
Form:
crystalline powder, powder, crystals or chunks
Solubility:
water: soluble(lit.)
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grade

ACS reagent

Quality Level

vapor density

1.7 (vs air)

vapor pressure

1 mmHg ( 817 °C)

assay

≥95.0%

form

crystalline powder, powder, crystals or chunks

pH

11-12 (25 °C, 49 g/L)

mp

563.7 °C (lit.)

solubility

water: soluble(lit.)

anion traces

S2-: ≤0.005%, SCN-: ≤0.02%, chloride (Cl-): ≤0.15%, phosphate (PO43-): ≤0.02%, sulfate (SO42-): ≤0.05%

cation traces

Fe: ≤0.005%, Pb: ≤0.005%

SMILES string

[Na]C#N

InChI

1S/CN.Na/c1-2;

InChI key

RTVFYQXEHKQMKO-UHFFFAOYSA-N

General description

Sodium cyanide is colorless sodium salt and its crystals belong to the cubic crystal system. Its aqueous solutions are strongly basic due to the presence of cyanide ion. It can be synthesized by reacting sodium hydroxide with hydrogen cyanide. Sodium cyanide is a key precursor for the synthesis of various organic intermediates. It participates in the RuCl3-mediated oxidative cyanation of tertiary amines.

Application

Sodium cyanide may be employed for the synthesis of the following compounds:
  • α-amino acids
  • Prussian blue (cyanide pigment)
  • nitriles, via reaction with primary and secondary chlorides


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signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 1 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 1

target_organs

Thyroid

supp_hazards

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Daniela Gontero et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 19(9), 1168-1188 (2020-07-18)
Escherichia coli bacteria were determined by in flow cytometry with laser excitation and fluorescence detection applying ultraluminescent core-shell nanoparticles based on Metal Enhanced Fluorescence (MEF). Core-shell nanoparticles consisted of a 40 nm core modified with a silica spacer grafted with
Eagleson M.
Concise Encyclopedia Chemistry, 1037-1037 (1994)
Preparation of Nitriles from Halides and Sodium Cyanide. An Advantageous Nucleophilic Displacement in Dimethyl Sulfoxide1a.
Friedman L and Shechter H.
The Journal of Organic Chemistry, 25(6), 877-879 (1960)



全球贸易项目编号

货号GTIN
205222-100G04061835346486
205222-500G04061835346509
205222-2.5KG04061835346493