蒸汽压
1 mmHg ( 970 °C)
方案
99%
表单
powder
反应适用性
reagent type: catalyst
core: zinc
mp
872 °C (lit.)
密度
4.95 g/mL at 25 °C (lit.)
SMILES字符串
F[Zn]F
InChI
1S/2FH.Zn/h2*1H;/q;;+2/p-2
InChI key
BHHYHSUAOQUXJK-UHFFFAOYSA-L
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一般描述
氟化锌是一种路易斯酸催化剂，可用于多种反应，包括酯化、Mukaiyama 醛醇反应、Mannich 反应、Friedel-Crafts 烷基化和烯丙化。它也可以用作许多催化转化的添加剂。
应用
氟化锌可以作为催化剂，通过不对称曼尼希反应合成光学活性 β-氨基酮和酯。
警示用语：
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
此项目有
Zinc Fluoride
Turcotte-Savard M, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Theoretical studies of valence orbital binding energies in solid zinc sulfide, zinc oxide, and zinc fluoride.
Tossell JA.
Inorganic Chemistry, 16(11), 2944-2949 (1977)
Novel sol-gel prepared zinc fluoride: synthesis, characterisation and acid-base sites analysis.
Guo Y, et al.
Journal of Materials Chemistry, 22(29), 14587-14593 (2009)
Tomoaki Hamada et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(4), 1205-1215 (2005-11-04)
Catalytic asymmetric Mannich-type reactions of an alpha-hydrazono ester with silicon enolates in aqueous media have been developed by using ZnF2 and chiral diamines as catalysts. In these reactions, both Zn2+ and a fluoride anion were necessary to achieve high yields
J L Lello et al.
International journal of oral and maxillofacial surgery, 17(4), 249-252 (1988-08-01)
To study the influence of interdental loop-wire splinting and intermaxillary fixation on the marginal gingiva, 30 patients were evaluated clinically using different periodontal parameters, at 5 examination times. It was shown that despite a standardized oral hygiene regime including the
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