蒸汽压
1 mmHg ( 970 °C)
方案
99%
表单
powder
反应适用性
reagent type: catalyst
core: zinc
mp
872 °C (lit.)
密度
4.95 g/mL at 25 °C (lit.)
SMILES字符串
F[Zn]F
InChI
1S/2FH.Zn/h2*1H;/q;;+2/p-2
InChI key
BHHYHSUAOQUXJK-UHFFFAOYSA-L
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一般描述
氟化锌是一种路易斯酸催化剂,可用于多种反应,包括酯化、Mukaiyama 醛醇反应、Mannich 反应、Friedel-Crafts 烷基化和烯丙化。它也可以用作许多催化转化的添加剂。
应用
氟化锌可以作为催化剂,通过不对称曼尼希反应合成光学活性 β-氨基酮和酯。
警示用语:
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
Zinc Fluoride
Turcotte-Savard M, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Novel sol-gel prepared zinc fluoride: synthesis, characterisation and acid-base sites analysis.
Guo Y, et al.
Journal of Materials Chemistry, 22(29), 14587-14593 (2009)
Theoretical studies of valence orbital binding energies in solid zinc sulfide, zinc oxide, and zinc fluoride.
Tossell JA.
Inorganic Chemistry, 16(11), 2944-2949 (1977)
J V Embleton et al.
Applied and environmental microbiology, 64(9), 3503-3506 (1998-09-03)
This study evaluated the susceptibility to amine fluorides (AmFs) of planktonic and biofilm cultures of Streptococcus sanguis grown with and without sucrose. Cultures were incubated with AmFs (250 mg of fluoride liter-1) for 1 min. The susceptibility of biofilms was
F Barbakow et al.
ASDC journal of dentistry for children, 51(1), 24-28 (1984-01-01)
Zinc in combination with hexetidine has been shown to be an effective chemical antiplaque agent clinically and in the laboratory. The effects of zinc fluoride on ground human enamel were studied by SEM and the sizes and numbers of the
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