208221
一氯化碘
reagent grade, ≥95%
别名:
氯化碘
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关于此项目
线性分子式:
ICl
化学文摘社编号:
分子量:
162.36
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
232-236-7
MDL number:
Assay:
≥95%
Grade:
reagent grade
Form:
solid or liquid
grade
reagent grade
Quality Level
assay
≥95%
form
solid or liquid
bp
97.4 °C (lit.)
density
3.24 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
ClI
InChI
1S/ClI/c1-2
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
General description
一氯化碘是一种卤素间化合物。它可与乙基、异丙基和叔丁基苯形成多种络合物。通过极性溶剂中溶解一氯化碘，可获得一氯化碘导电溶液。一氯化碘是一种绿色氧化剂，参与以下转化过程：
- 醛糖半缩醛对应相应的醛糖内酯
- 二芳基甲醇与相应的二芳基甲酮
- 芳基烷基甲醇与相应的芳基烷基甲酮
- 二烷基甲醇与相应的二烷基甲酮
Application
一氯化碘（ICl）试剂可用于以下过程：
- 甲氧基和二甲氧基苯的卤化
- 黄酮的合成。
- 1-萘醛的制备。
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
存储类别
8A - Combustible corrosive hazardous materials
法规信息
危险化学品
此项目有
Synthesis of 1-naphthaldehydes via the cascade reactions of 1-phenylpent-4-yn-2-ols promoted by iodine monochloride
Li B, et al.
Tetrahedron Letters, 57.17, 1843-1846 (2016)
Iodine Monochloride (ICl) as a Highly Efficient, Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds
Wei, Peng, et al.
Synthetic Communications, 45.12, 1457-1470 (2015)
A mild and convenient procedure for conversion of alkenes into alkyl iodides via reaction of iodine monochloride with organoboranes.
Kabalka GW and Gooch III EE.
The Journal of Organic Chemistry, 45(18), 3578-3580 (1980)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 208221-250G | 04061838769558 |
| 208221-100G | 04061838769541 |
| 208221-5G | 04061838769565 |