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关于此项目
经验公式(希尔记法):
HI
化学文摘社编号:
分子量:
127.91
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352106
MDL number:
产品名称
氢碘酸, contains no stabilizer, distilled, 57 wt. % in H2O, 99.99% trace metals basis
InChI
1S/HI/h1H
SMILES string
I
InChI key
XMBWDFGMSWQBCA-UHFFFAOYSA-N
assay
99.99% trace metals basis
form
liquid
does not contain
stabilizer
concentration
57 wt. % in H2O
bp
127 °C (lit.)
mp
-50 °C
density
1.701 g/mL at 25 °C
storage temp.
room temp
Quality Level
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Application
氢碘酸可用于合成三氘-[13C]-甲基碘和[13C]-甲基碘。
General description
氢碘酸是溶于水的碘化氢气体。它是强酸,通常用作还原剂。
氢碘酸(HI)和红磷(HI/红P)在甲基苯丙胺制备中起到还原剂的作用。HI/磷会引发各种多环醌发生还原反应。HI还可作为还原剂参与将各种聚芳烃醌、氢醌和酚转化成相应的芳烃。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
A practical laboratory route to the synthesis of trideuteriomethyl-[13C] iodide.
Coumbarides GS, et al.
Journal of Labelled Compounds & Radiopharmaceuticals, 46(4), 291-296 (2003)
Patnaik P.
A Comprehensive Guide to the Hazardous Properties of Chemical Substances, 123 (2007)
Efficient reduction of polycyclic quinones, hydroquinones, and phenols with hydriodic acid.
Konieczny M and Harvey RG.
The Journal of Organic Chemistry, 44(26), 4813-4816 (1979)
Methamphetamine synthesis via hydriodic acid/red phosphorus reduction of ephedrine.
Skinner HF.
Forensic Science International, 48(2), 123-134 (1990)
Kazumasa Wakamatsu et al.
Pigment cell & melanoma research, 22(4), 474-486 (2009-06-06)
Pheomelanogenesis is a complex pathway that starts with the oxidation of tyrosine (or DOPA, 3,4-dihydroxyphenylalanine) by tyrosinase in the presence of cysteine, which results in the production of 5-S-cysteinyldopa and its isomers. Beyond that step, relatively little has been clarified
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