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Merck
CN

210250

硫酸羟胺

99%

别名:

硫酸胲

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关于此项目

线性分子式:
(NH2OH)2 · H2SO4
化学文摘社编号:
分子量:
164.14
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
233-118-8
MDL number:
Assay:
99%
Form:
crystals
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Quality Level

assay

99%

form

crystals

mp

170 °C (dec.) (lit.)

SMILES string

NO.NO.OS(O)(=O)=O

InChI

1S/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4)

InChI key

VRXOQUOGDYKXFA-UHFFFAOYSA-N

General description

Cyclohexanone oxime undergoes hydrolytic reaction with sulfuric acid to yield hydroxylamine sulfate. It reacts with sulfur dioxide to afford sulfamic acid.

Application

Hydroxylamine sulfate may be used in the following:
  • Along with NaCl for reduction during the atomic absorption spectrophotometric quantification of mercury at ppb (parts-per-billion) levels in solution.
  • As one of the constituents during the preparation of a coloring solution, impregnated in a cellulose based monitoring tape for the sensitive detection of formaldehyde gas.
  • Simultaneous estimation of hydrarine and hydroxylamine in mixtures by titration with alkaline ferricyanide in presence of zinc sulfate.
强还原剂。可将醛和酮转化为肟,将酰基氯转化为氧肟酸。可用作聚合过程中的催化剂、溶胀剂和共聚反应抑制剂。


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Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral

target_organs

Blood

存储类别

4.1A - Other explosive hazardous materials

wgk

WGK 3

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A simple and efficient approach for preparation of hydroxylamine sulfate from the acid-catalyzed hydrolysis reaction of cyclohexanone oxime.
Zhao, Fangfang, et al.
Chemical Engineering Journal, 272, 102-107 (2015)
The Preparation of Sulfamic Acid by the Hydroxylamine--Sulfur Dioxide Reaction.
Sisler HH and Audrieth LF.
Journal of the American Chemical Society, 61(12), 3389-3391 (1939)
Development of a monitoring tape for formaldehyde using hydroxylamine sulfate and methyl yellow.
NAKANO N, et al.
Analytical Sciences, 10(4), 641-645 (1994)



全球贸易项目编号

货号GTIN
210250-1KG04061838771209
210250-100G04061838771193