210250
硫酸羟胺
99%
别名:
硫酸胲
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关于此项目
线性分子式:
(NH2OH)2 · H2SO4
化学文摘社编号:
分子量:
164.14
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21
质量水平
方案
99%
表单
crystals
mp
170 °C (dec.) (lit.)
SMILES字符串
NO.NO.OS(O)(=O)=O
InChI
1S/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4)
InChI key
VRXOQUOGDYKXFA-UHFFFAOYSA-N
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一般描述
Cyclohexanone oxime undergoes hydrolytic reaction with sulfuric acid to yield hydroxylamine sulfate. It reacts with sulfur dioxide to afford sulfamic acid.
应用
强还原剂。可将醛和酮转化为肟，将酰基氯转化为氧肟酸。可用作聚合过程中的催化剂、溶胀剂和共聚反应抑制剂。
Hydroxylamine sulfate may be used in the following:
- Along with NaCl for reduction during the atomic absorption spectrophotometric quantification of mercury at ppb (parts-per-billion) levels in solution.
- As one of the constituents during the preparation of a coloring solution, impregnated in a cellulose based monitoring tape for the sensitive detection of formaldehyde gas.
- Simultaneous estimation of hydrarine and hydroxylamine in mixtures by titration with alkaline ferricyanide in presence of zinc sulfate.
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral
靶器官
Blood
储存分类代码
4.1A - Other explosive hazardous materials
WGK
WGK 3
法规信息
危险化学品
此项目有
A simple and efficient approach for preparation of hydroxylamine sulfate from the acid-catalyzed hydrolysis reaction of cyclohexanone oxime.
Zhao, Fangfang, et al.
Chemical Engineering Journal, 272, 102-107 (2015)
The Preparation of Sulfamic Acid by the Hydroxylamine--Sulfur Dioxide Reaction.
Sisler HH and Audrieth LF.
Journal of the American Chemical Society, 61(12), 3389-3391 (1939)
Determination of submicrogram quantities of mercury by atomic absorption spectrophotometry.
Hatch WR and Ott WL.
Analytical Chemistry, 40(14), 2085-2087 (1968)
Marzhan Sypabekova et al.
Biosensors & bioelectronics, 165, 112365-112365 (2020-07-31)
A miniature biosensing platform based on MgO-based nanoparticle doped optical fiber was developed for the biomolecule detection. The technology used a single mode fiber with MgO-based nanoparticles doped core. The detection was based on collecting the Rayleigh backscattering signatures with
Development of a monitoring tape for formaldehyde using hydroxylamine sulfate and methyl yellow.
NAKANO N, et al.
Analytical Sciences, 10(4), 641-645 (1994)
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