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Merck
CN

224332

氯化亚铜

ReagentPlus®, purified, ≥99%

别名:

一氯化铜

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关于此项目

线性分子式:
CuCl
化学文摘社编号:
分子量:
99.00
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-842-9
MDL number:
Assay:
≥99%
Form:
powder
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InChI key

OXBLHERUFWYNTN-UHFFFAOYSA-M

InChI

1S/ClH.Cu/h1H;/q;+1/p-1

SMILES string

Cl[Cu]

vapor pressure

1.3 mmHg ( 546 °C)

product line

ReagentPlus®

assay

≥99%

form

powder

reaction suitability

reagent type: catalyst
core: copper

pH

5 (20 °C, 50 g/L)

bp

1490 °C (lit.)

mp

430 °C (lit.)

Quality Level

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Application

作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。
氯化铜(I)(CuCl)已被用于合成铜纳米环结构。 它还被用作在导电氮掺杂石墨烯(NG)上制备有序TiO2纳米阵列的前体。

General description

Cu在CuCl中以+1(亚铜)价态存在。CuCl是一种具有宽带隙的半导体。由于其晶格类似于硅,因此它是一种可用于硅基光电的有前途的候选材料。它可与格氏试剂一起参与各种反应。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Solvothermal synthesis and mechanical characterization of single crystalline copper nanorings.
Zhan Y, et al.
Journal of Crystal Growth, 325(1), 76-80 (2011)
Shuxin Wang et al.
Nature communications, 8(1), 848-848 (2017-10-12)
It has long been a challenge to dope metal nanoparticles with a specific number of heterometal atoms at specific positions. This becomes even more challenging if the heterometal belongs to the same group as the host metal because of the
Network of Heterogeneous Catalyst Arrays on the Nitrogen-Doped Graphene for Synergistic Solar Energy Harvesting of Hydrogen from Water.
Shin, Sang Rim, et al.
Chemistry of Materials (2016)
Erwan Gicquel et al.
Biomacromolecules, 20(7), 2545-2556 (2019-06-28)
This study investigates the adsorption of a block copolymer composed of a poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) cationic polyelectrolyte and a poly(di(ethylene glycol) methyl ethermethacrylate) (PDEGMA) on oxidized cellulose nanocrystals (TO-CNCs) to produce hydrogels. PDMEAMA- b-PDEGMA was synthesized by atom-transfer radical polymerization.

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