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Merck
CN

227676

硫酸镍(II) 六水合物

ACS reagent, ≥98%

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关于此项目

线性分子式:
NiSO4 · 6H2O
化学文摘社编号:
分子量:
262.85
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-104-9
MDL number:
Assay:
≥98%
Grade:
ACS reagent
Form:
crystals
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grade

ACS reagent

Quality Level

vapor density

2.07 (vs air)

assay

≥98%

form

crystals

reaction suitability

reagent type: catalyst
core: nickel

impurities

≤0.002% N compounds, ≤0.005% insolubles

anion traces

chloride (Cl-): ≤0.001%

cation traces

Ca: ≤0.005%, Co: ≤0.002%, Cu: ≤0.005%, Fe: ≤0.001%, K: ≤0.01%, Mg: ≤0.005%, Mn: ≤0.002%, Na: ≤0.05%

SMILES string

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

InChI key

RRIWRJBSCGCBID-UHFFFAOYSA-L

General description

硫酸镍(II)六水合物是一种水合镍盐。它可用作制备镍基催化剂的镍前驱体。

Application

硫酸镍(II)六水合物(NiSO4 6H2O)可作为镍前体,用于制备:     
  • 钯-镍双金属纳米颗粒(Pd-Ni),用于催化 Buchwald-Hartwig胺化反应。
  • NiFe2O4 纳米粒子(NPs),应用于制备葡萄糖生物传感器。

它还可作为可回收催化剂用于:      
  • 通过芳香醛、伯胺和亚磷酸二乙酯一锅法三组分反应合成 α-氨基磷酸酯。      
  • 在Langlois′ 试剂(CF3SO2Na)作为CF3 源和过硫酸钾(K2S2O8)作为引发剂参与下的芳基胺三氟甲基化。



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signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

法规信息

危险化学品

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全球贸易项目编号

货号GTIN
227676-2.5KG04061837768781
227676-500G04061837768798
227676-100G04061838780867