234125
亚铁氰化铁
别名:
二铁铁素, 亚铁氰化铁, 六氰基铁酸铁, 普鲁士蓝
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关于此项目
线性分子式:
Fe4[Fe(CN)6]3
化学文摘社编号:
分子量:
859.23
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-875-5
MDL number:
Form:
powder
InChI key
DNMNDNSFJMUUFM-UHFFFAOYSA-N
InChI
1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3
SMILES string
[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N
form
powder
concentration
≥30% (ICP)
λmax
694 nm
Quality Level
Application
亚铁氰化铁可用于：
- 作为催化剂催化二氧化碳和环氧化物反应合成环状碳酸酯。
- 作为前体经热解制备N-掺杂多层石墨烯包裹的Fe-Fe3C纳米颗粒。
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Lihua Jin et al.
Chemical communications (Cambridge, England), 49(3), 243-245 (2012-11-24)
A highly robust electrochemically controlled fluorescence switch based on ultrasmall Au nanoclusters has been designed by the aid of the electrochemical redox reaction of prussian blue.
Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues.
Itaya K, et al.
Accounts of Chemical Research, 19(6), 162-168 (1986)
Prussian blue as a single precursor for synthesis of Fe/Fe3C encapsulated N-doped graphitic nanostructures as bi-functional catalysts
Barman BK and Nanda KK
Green Chemistry, 18(2), 427-432 (2016)
High conversion of CO2 into cyclic carbonates under solvent-free and ambient pressure conditions by a Fe-cyanide complex
Jiang P, et al.
New. J. Chem., 43(44), 17211-17219 (2019)
Hassina Baraki et al.
PloS one, 7(12), e51770-e51770 (2012-12-14)
We sought to detect an acute soft tissue infection in rats by magnetic resonance imaging (MRI) using granulocytes, previously labeled with superparamagnetic particles of iron oxide (SPIO). Parasternal infection was induced by subcutaneous inoculation of Staphylococcus aureus suspension in rats.
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