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Merck
CN

237051

氯化铝

ReagentPlus®, 99%

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关于此项目

线性分子式:
AlCl3
化学文摘社编号:
分子量:
133.34
PubChem Substance ID:
eCl@ss:
38120507
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
231-208-1
MDL number:
Assay:
99%
Form:
powder
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vapor pressure

1 mmHg ( 100 °C)

Quality Level

product line

ReagentPlus®

assay

99%

form

powder

reaction suitability

reagent type: catalyst
core: aluminum

pH

2.4 (20 °C, 100 g/L)

mp

190 °C (lit.)

SMILES string

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VSCWAEJMTAWNJL-UHFFFAOYSA-K

General description

氯化铝是一种醇溶性路易斯酸。† 氯化铝与硼氢化钠在二甘醇中以摩尔比混合,得到具有强还原性属性混合物。† 据报道,它促进 4-丁基苯甲酰氯与均三甲苯之间的 Friedel-Crafts 酰化反应。†

Application

氯化铝用于以下研究:
  • 苯聚合生成 p-聚苯。
  • 作为 buckymetallocenes 与酸氯化物的 Friedel-Crafts 酰化的催化剂。
  • 作为用于测定脂质氢过氧化物的比色法微量测定的催化剂。

Features and Benefits

氢与其他金属卤化物的气相共还原作用可用于金属间的精细分离,可作为结构材料或化合物使用,具有重要热电、磁和抗氧化性能。 氮化铝可以由添加了AlCl3 的元素合成,以促进结晶。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused
Yutaka Matsuo et al.
Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)



全球贸易项目编号

货号GTIN
237051-5G04061838785916
237051-100G04061834311324
237051-500G04061838785909