237051
氯化铝
ReagentPlus®, 99%
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关于此项目
线性分子式:
AlCl3
化学文摘社编号:
分子量:
133.34
PubChem Substance ID:
eCl@ss:
38120507
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
231-208-1
MDL number:
Assay:
99%
Form:
powder
产品名称
氯化铝, ReagentPlus®, 99%
InChI key
VSCWAEJMTAWNJL-UHFFFAOYSA-K
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
SMILES string
Cl[Al](Cl)Cl
vapor pressure
1 mmHg ( 100 °C)
product line
ReagentPlus®
assay
99%
form
powder
reaction suitability
reagent type: catalyst
core: aluminum
pH
2.4 (20 °C, 100 g/L)
mp
190 °C (lit.)
Quality Level
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Application
氯化铝用于以下研究：
- 苯聚合生成 p-聚苯。
- 作为 buckymetallocenes 与酸氯化物的 Friedel-Crafts 酰化的催化剂。
- 作为用于测定脂质氢过氧化物的比色法微量测定的催化剂。
Features and Benefits
氢与其他金属卤化物的气相共还原作用可用于金属间的精细分离，可作为结构材料或化合物使用，具有重要热电、磁和抗氧化性能。 氮化铝可以由添加了AlCl3 的元素合成，以促进结晶。
General description
氯化铝是一种醇溶性路易斯酸。† 氯化铝与硼氢化钠在二甘醇中以摩尔比混合，得到具有强还原性属性混合物。† 据报道，它促进 4- 叔丁基苯甲酰氯与均三甲苯之间的 Friedel-Crafts 酰化反应。†
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
Detection of Alternative Oxidase Expression in Arabidopsis thaliana Protoplasts Treated with Aluminium.
Liu J, et al.
Bio-protocol, 5(13) (2015)
Shutao Wang et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 5(4), 1700712-1700712 (2018-05-04)
In the search for low-cost and large-scale stationary storage of electricity, nonaqueous aluminum chloride-graphite batteries (AlCl3-GBs) have received much attention due to the high natural abundances of their primary constituents, facile manufacturing, and high energy densities. Much research has focused
Yutaka Matsuo et al.
Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
Acylated buckyferrocene and ruthenocene, Fe(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me, Ph, and CH[double bond, length as m-dash]CHPh) and Ru(η(5)-C60Me5)(η(5)-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in
Rajkumar Kore et al.
Dalton transactions (Cambridge, England : 2003), 47(23), 7795-7803 (2018-06-01)
Two solids of differing Lewis acidities, triethylammonium tetrachlorozincate ([HN222]2[ZnCl4]) and AlCl3, have been combined across 0.1 to 0.9 mole fractions (with respect to [HN222]2[ZnCl4]), and homogeneous solid double salts or mixed metal [HN222]2x[(1 - x)AlCl3 + xZnCl4] double salt ionic
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