244120
过硼酸钠 四水合物
9-11% available Oxygen
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线性分子式:
NaBO3 · 4H2O
化学文摘社编号:
分子量:
153.86
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
239-172-9
MDL number:
Form:
powder or granules
产品名称
过硼酸钠 四水合物, 9-11% available Oxygen
InChI key
IBDSNZLUHYKHQP-UHFFFAOYSA-N
InChI
1S/BO3.Na.4H2O/c2-1-3-4-1;;;;;/h;;4*1H2/q-1;+1;;;;
SMILES string
O.O.O.O.[Na+].[O-]B1OO1
form
powder or granules
quality
9-11% available Oxygen
concentration
~6.5-7.5% NaOH (titration)
~9-11% (active oxygen basis (by Na2S2O3, titration))
pH
10-10.4 (25 °C, 10 g/L)
mp
60 °C (dec.) (lit.)
Quality Level
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Application
Sodium perborate tetrahydrate may be employed for the following studies:
- Transformation of iodoarenes to (diacetoxyiodo)arenes.
- Oxidation of Π-deficient azines to afford N-oxides.
- Oxidation of sulphur containing heterocyclic compounds to afford S,S-dioxides.
- Microwave-assisted oxidative hydration of various aromatic and aliphatic nitriles.
- Various oxidation reactions of anilines and sulphides.
- As a catalyst for the transformation of 2′-hydroxychalcones to flavanones.
General description
Sodium perborate is widely employed as an oxidizing agent.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Repr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Sodium perborate tetrahydrate?mediated transformations of 2'-hydroxychalcones to flavanones, flavones, and 3', 5'-diiodoflavone under mild, environmentally friendly conditions.
Ganguly NC, et al.
Synthetic Communications, 43(10), 1351-1361 (2013)
Further functional group oxidations using sodium perborate.
McKillop A and Kemp D.
Tetrahedron, 45(11), 3299-3306 (1989)
Functional group oxidation using sodium perborate1.
McKillop A and Tarbin JA.
Tetrahedron, 43(8), 1753-1758 (1987)
Microwave-promoted transformation of nitriles to amides with aqueous sodium perborate.
Sharifi A, et al.
Synthetic Communications, 31(3), 431-434 (2001)
Viviane Maia Barreto de Oliveira et al.
Gerodontology, 28(2), 134-139 (2009-09-29)
To determine the effectiveness of a denture cleanser in reducing the concentration of volatile sulphur compounds (VSC) and its antimicrobial action. Micro-organisms from the denture biofilm can cause local and systemic disease and halitosis. Denture cleansers are important adjuncts in
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