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Merck
CN

244120

过硼酸钠 四水合物

9-11% available Oxygen

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线性分子式:
NaBO3 · 4H2O
化学文摘社编号:
分子量:
153.86
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.55
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表单

powder or granules

质量水平

质量

9-11% available Oxygen

浓度

~6.5-7.5% NaOH (titration)
~9-11% (active oxygen basis (by Na2S2O3, titration))

pH值(酸碱度)

10-10.4 (25 °C, 10 g/L)

mp

60 °C (dec.) (lit.)

SMILES字符串

O.O.O.O.[Na+].[O-]B1OO1

InChI

1S/BO3.Na.4H2O/c2-1-3-4-1;;;;;/h;;4*1H2/q-1;+1;;;;

InChI key

IBDSNZLUHYKHQP-UHFFFAOYSA-N

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一般描述

Sodium perborate is widely employed as an oxidizing agent.

应用

Sodium perborate tetrahydrate may be employed for the following studies:
  • Transformation of iodoarenes to (diacetoxyiodo)arenes.
  • Oxidation of Π-deficient azines to afford N-oxides.
  • Oxidation of sulphur containing heterocyclic compounds to afford S,S-dioxides.
  • Microwave-assisted oxidative hydration of various aromatic and aliphatic nitriles.
  • Various oxidation reactions of anilines and sulphides.
  • As a catalyst for the transformation of 2′-hydroxychalcones to flavanones.

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Eye Dam. 1 - Repr. 1B - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

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Sodium perborate tetrahydrate?mediated transformations of 2'-hydroxychalcones to flavanones, flavones, and 3', 5'-diiodoflavone under mild, environmentally friendly conditions.
Ganguly NC, et al.
Synthetic Communications, 43(10), 1351-1361 (2013)
Microwave-promoted transformation of nitriles to amides with aqueous sodium perborate.
Sharifi A, et al.
Synthetic Communications, 31(3), 431-434 (2001)
Further functional group oxidations using sodium perborate.
McKillop A and Kemp D.
Tetrahedron, 45(11), 3299-3306 (1989)
Functional group oxidation using sodium perborate1.
McKillop A and Tarbin JA.
Tetrahedron, 43(8), 1753-1758 (1987)
Daniela Nair Borges Felipucci et al.
Brazilian dental journal, 22(5), 392-397 (2011-10-21)
Removable partial dentures (RPD) demand specific hygienic cleaning and the combination of brushing with immersion in chemical solutions has been the most recommended method for control of biofilm. However, the effect of the cleansers on metallic components has not been

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