等级
HPLC grade
质量水平
蒸汽密度
2.1 (vs air)
蒸汽压
2.7 mmHg
方案
≥96%
表单
liquid
自燃温度
784 °F
expl. lim.
7.3 %, 33 °F
技术
HPLC: suitable
杂质
<0.030% water
折射率
n20/D 1.382 (lit.)
pH值（酸碱度）
6.4 (20 °C, 0.01 g/L)
沸点
101.2 °C (lit.)
mp
−29 °C (lit.)
密度
1.127 g/mL at 25 °C (lit.)
λ
H2O reference
紫外吸收
λ: 380 nm Amax: 1.00
λ: 386 nm Amax: 0.50
λ: 395 nm Amax: 0.20
λ: 400 nm Amax: 0.10
λ: 405 nm Amax: 0.05
λ: 430-700 nm Amax: 0.01
应用
food and beverages
SMILES字符串
C[N+]([O-])=O
InChI
1S/CH3NO2/c1-2(3)4/h1H3
InChI key
LYGJENNIWJXYER-UHFFFAOYSA-N
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应用
- Asymmetric aza-Henry reaction toward trifluoromethyl β-nitroamines and biological investigation of their adamantane-type derivatives.: This study used nitromethane in asymmetric aza-Henry reactions to synthesize trifluoromethyl β-nitroamines, which were further investigated for their biological properties, showcasing the potential of nitromethane in advanced synthetic chemistry (Ren et al., 2024).
- Effect of Temperature on the Liquid Bridging Force while Maintaining Physical Stability in Solid-Liquid Mixed Fuel.: Nitromethane was analyzed in this research to understand its role in the stability of solid-liquid mixed fuels under varying temperatures, providing insights into the optimization of fuel formulations (Zhang et al., 2024).
- Generation of New Synthons for Synthesis Through Activation of Nitromethane.: This research demonstrated the activation of nitromethane to generate new synthons for synthetic applications, highlighting its versatility and importance in creating novel chemical entities (Wang et al., 2024).
- Towards Chemoenzymatic Syntheses of Both Enantiomers of Phosphoemeriamine.: The study explored the use of nitromethane in chemoenzymatic syntheses, enabling the production of both enantiomers of phosphoemeriamine, an important compound in chemical biology (Kiełbasiński et al., 2024).
- Rationally introducing non-canonical amino acids to enhance catalytic activity of LmrR for Henry reaction.: Nitromethane was employed in this study to investigate the enhancement of catalytic activity in the Henry reaction through the introduction of non-canonical amino acids, demonstrating its significance in enzyme catalysis research (Wang et al., 2024).
警示用语：
Warning
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2
储存分类代码
4.1A - Other explosive hazardous materials
WGK
WGK 2
闪点(°F)
95.0 °F - closed cup
闪点(°C)
35 °C - closed cup
法规信息
危险化学品
易制爆化学品
The catalytic chemistry of nitromethane over Co-ZSM5 and other catalysts in connection with the methane-NOxSCR reaction.
Cowan AD, et al.
J. Catal., 176(2), 329-343 (1998)
Metal ion encapsulation: cobalt cages derived from polyamines, formaldehyde, and nitromethane.
Geue RJ, et al.
Journal of the American Chemical Society, 106(19), 5478-5488 (1984)
Benedek Vakulya et al.
Organic letters, 7(10), 1967-1969 (2005-05-07)
Cinchona alkaloid-derived chiral bifunctional thiourea organocatalysts were synthesized and applied in the Michael addition between nitromethane and chalcones with high ee and chemical yields.
Eagleson M.
Concise Encyclopedia Chemistry, 696-696 (1994)
Wenguo Yang et al.
Chemistry, an Asian journal, 7(4), 771-777 (2012-02-10)
Through the cleavage of the C-C bond, the first catalytic tandem conjugate addition-elimination reaction of Morita-Baylis-Hillman C adducts has been presented. Various S(N)2'-like C-, S-, and P-allylic compounds could be obtained with exclusive E configuration in good to excellent yields.
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