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Merck
CN

310263

Sigma-Aldrich

碳酸钾

ReagentPlus®, 99%

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线性分子式:
K2CO3
化学文摘社编号:
分子量:
138.21
Beilstein:
4267587
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.21
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质量水平

产品线

ReagentPlus®

方案

99%

表单

solid

pH值(酸碱度)

11-13 (25 °C, 138 g/L)

mp

891 °C (lit.)

SMILES字符串

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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一般描述

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene. Addition of amino acids (glycine, sarcosine and proline) to K2CO3 (solvent) promotes the absorption of CO2.

应用

Potassium carbonate may be used in the following processes:
  • As a reagent in the synthesis of polysubstituted iodobenzene derivatives.
  • As a base for the Suzuki coupling of aryl halides with aryl boronic acids.
  • The Heck reaction of styrene and bromobenzene.
  • Preparation of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone, a disulfonated diamine monomer.

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

13 - Non Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A kinetic study of CO2 capture with potassium carbonate solutions promoted with various amino acids: glycine, sarcosine and proline.
Thee H, et al.
International Journal of Greenhouse Gas Control, 20, 212-222 (2014)
Robert Möckel et al.
Organic letters, 17(7), 1644-1647 (2015-03-21)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction.
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
Herrmann WA, et al.
Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
Heck reaction using palladium complexed to dendrimers on silica.
Alper H, et al.
Canadian Journal of Chemistry, 78(6), 920-924 (2000)
Polyamide interfacial composite membranes prepared from m-phenylene diamine, trimesoyl chloride and a new disulfonated diamine.
Xie W, et al.
Journal of Membrane Science, 403, 152-161 (2012)

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