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关于此项目
线性分子式:
SbCl3
化学文摘社编号:
分子量:
228.12
PubChem Substance ID:
eCl@ss:
38080204
UNSPSC Code:
12352302
NACRES:
NB.24
EC Number:
233-047-2
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Form:
powder, crystals or chunks
产品名称
氯化锑(III), ACS reagent, ≥99.0%
InChI key
FAPDDOBMIUGHIN-UHFFFAOYSA-K
InChI
1S/3ClH.Sb/h3*1H;/q;;;+3/p-3
SMILES string
Cl[Sb](Cl)Cl
grade
ACS reagent
vapor density
7.9 (vs air)
vapor pressure
1 mmHg ( 49 °C)
assay
≥99.0%
form
powder, crystals or chunks
reaction suitability
reagent type: catalyst
core: antimony
impurities
≤0.05% insol. CHCl3
mp
73.4 °C (lit.)
anion traces
sulfate (SO42-): ≤0.005%
cation traces
As: ≤0.02%
Ca: ≤0.005%
Cu: ≤0.001%
Fe: ≤0.002%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.005%
Quality Level
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Application
氯化锑(III)(SbCl3)是一种路易斯酸催化剂,用于各种有机反应,如聚合、Friedel-Crafts 酰化、NaBH4 还原、环氧化合物开环、三烷基醚裂解、Biginelli 反应和氯化反应。它也被用作合成其他锑盐的前体。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
Synthesis, structural characterization and cytotoxicity of the antimony (III) chloride complex with N, N-dicyclohexyldithiooxamide.
Ozturk II, et al.
Polyhedron, 52, 1403-1410 (2013)
Nucleic acid related compounds. 79. Efficient conversions of thioethers to. alpha.-fluoro thioethers with DAST or DAST/antimony (III) chloride.
Robins MJ and Wnuk SF.
The Journal of Organic Chemistry, 58(15), 3800-3800 (1993)
Antimony (III) chloride-catalyzed ring opening of epoxides with anilines.
Singh MC and Peddinti RK.
Tetrahedron Letters, 48(41), 7354-7357 (2007)
Antimony (III) chloride-catalysed Biginelli reaction: a versatile method for the synthesis of dihydropyrimidinones through a different reaction mechanism
Cepanec I, et al.
Tetrahedron, 63(48), 11822-11827 (2007)
N Gurnani et al.
Cytobios, 70(281), 131-136 (1992-01-01)
Clastogenic effects of antimony trichloride, used in small industries, were monitored in laboratory bred white Swiss mice in vivo, following oral administration by gavaging, after 6, 12, 18 and 24 h. Chromosomal aberrations were principally breaks and damaged cells observed
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