311375
氯化锑(III)
ACS reagent, ≥99.0%
别名:
三氯化锑
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关于此项目
线性分子式:
SbCl3
CAS Number:
分子量:
228.12
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38080204
PubChem化学物质编号:
NACRES:
NB.24
等级
ACS reagent
质量水平
蒸汽密度
7.9 (vs air)
蒸汽压
1 mmHg ( 49 °C)
方案
≥99.0%
表单
powder, crystals or chunks
反应适用性
reagent type: catalyst
core: antimony
杂质
≤0.05% insol. CHCl3
mp
73.4 °C (lit.)
痕量阴离子
sulfate (SO42-): ≤0.005%
痕量阳离子
As: ≤0.02%
Ca: ≤0.005%
Cu: ≤0.001%
Fe: ≤0.002%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.005%
SMILES字符串
Cl[Sb](Cl)Cl
InChI
1S/3ClH.Sb/h3*1H;/q;;;+3/p-3
InChI key
FAPDDOBMIUGHIN-UHFFFAOYSA-K
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应用
氯化锑(III)（SbCl3）是一种路易斯酸催化剂，用于各种有机反应，如聚合、Friedel-Crafts 酰化、NaBH4 还原、环氧化合物开环、三烷基醚裂解、Biginelli 反应和氯化反应。它也被用作合成其他锑盐的前体。
警示用语：
Danger
危险声明
危险分类
Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
危险化学品
Synthesis, structural characterization and cytotoxicity of the antimony (III) chloride complex with N, N-dicyclohexyldithiooxamide.
Ozturk II, et al.
Polyhedron, 52, 1403-1410 (2013)
Nucleic acid related compounds. 79. Efficient conversions of thioethers to. alpha.-fluoro thioethers with DAST or DAST/antimony (III) chloride.
Robins MJ and Wnuk SF.
The Journal of Organic Chemistry, 58(15), 3800-3800 (1993)
Antimony (III) chloride-catalyzed ring opening of epoxides with anilines.
Singh MC and Peddinti RK.
Tetrahedron Letters, 48(41), 7354-7357 (2007)
Antimony (III) chloride-catalysed Biginelli reaction: a versatile method for the synthesis of dihydropyrimidinones through a different reaction mechanism
Cepanec I, et al.
Tetrahedron, 63(48), 11822-11827 (2007)
T Gebel et al.
Anticancer research, 18(6A), 4253-4257 (1999-01-19)
Antimony compounds are supposed to resemble to arsenicals in some toxicological features. Comparative investigations with antimony and arsenic were performed to collect data on the genotoxicity of antimony, on which the knowledge is scarce. In comparison to trivalent arsenic, trivalent
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