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线性分子式:
NaIO4
化学文摘社编号:
分子量:
213.89
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-197-6
MDL number:
Assay:
≥99.8%
99.8-100.3% dry basis (ACS specification)
99.8-100.3% dry basis (ACS specification)
Grade:
ACS reagent
Form:
crystalline powder
产品名称
高碘酸钠, ACS reagent, ≥99.8%
InChI key
JQWHASGSAFIOCM-UHFFFAOYSA-M
InChI
1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
SMILES string
[Na+].[O-]I(=O)(=O)=O
grade
ACS reagent
assay
≥99.8%
99.8-100.3% dry basis (ACS specification)
form
crystalline powder
reaction suitability
reagent type: oxidant
impurities
≤0.02% other halogens (as Cl)
pH
3.5-5.5 (25 °C, 107 g/L)
mp
300 °C (dec.) (lit.)
cation traces
Mn: ≤3 ppm
storage temp.
room temp
Quality Level
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Application
高碘酸钠可用作氧化剂:
- 将硫化物选择性氧化为亚砜。
- 氧化裂解各种 1,2-二醇以生成醛类或酮类。
- 将二芳基、二烷基和芳基烷基硒化物氧化为各自的硒氧化物。
- 选择性烯烃环氧化和烷烃羟基化反应。
- 选择性氧化活性纤维素,以通过裂解葡萄糖单元中 C2 – C3 之间的键得到双醛纤维素(DAC)。
- 它还可用作芳烃和卤素化合物的碘化剂。
General description
高碘酸钠是一种无机盐,通常用作各种有机底物的氧化剂和其他一些氧化反应的助氧化剂。高碘酸钠的氧化发生在水介质中,但有机助溶剂用于不溶于水的有机基质。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1
target_organs
Thyroid
存储类别
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
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