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Merck
CN

311448

高碘酸钠

ACS reagent, ≥99.8%

别名:

(偏)高碘酸钠

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线性分子式:
NaIO4
化学文摘社编号:
分子量:
213.89
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-197-6
MDL number:
Assay:
≥99.8%
99.8-100.3% dry basis (ACS specification)
Grade:
ACS reagent
Form:
crystalline powder
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产品名称

高碘酸钠, ACS reagent, ≥99.8%

InChI key

JQWHASGSAFIOCM-UHFFFAOYSA-M

InChI

1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

SMILES string

[Na+].[O-]I(=O)(=O)=O

grade

ACS reagent

assay

≥99.8%
99.8-100.3% dry basis (ACS specification)

form

crystalline powder

reaction suitability

reagent type: oxidant

impurities

≤0.02% other halogens (as Cl)

pH

3.5-5.5 (25 °C, 107 g/L)

mp

300 °C (dec.) (lit.)

cation traces

Mn: ≤3 ppm

storage temp.

room temp

Quality Level

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Application

高碘酸钠可用作氧化剂:
  • 将硫化物选择性氧化为亚砜。
  • 氧化裂解各种 1,2-二醇以生成醛类或酮类。
  • 将二芳基、二烷基和芳基烷基硒化物氧化为各自的硒氧化物。
  • 选择性烯烃环氧化和烷烃羟基化反应。
  • 选择性氧化活性纤维素,以通过裂解葡萄糖单元中 C2 – C3 之间的键得到双醛纤维素(DAC)。
  • 它还可用作芳烃和卤素化合物的碘化剂。

General description

高碘酸钠是一种无机盐,通常用作各种有机底物的氧化剂和其他一些氧化反应的助氧化剂。高碘酸钠的氧化发生在水介质中,但有机助溶剂用于不溶于水的有机基质。

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1

target_organs

Thyroid

存储类别

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品
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