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线性分子式:
K3Fe(CN)6
化学文摘社编号:
分子量:
329.24
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-323-3
MDL number:
Assay:
≥99%
Form:
crystalline
InChI key
MIMJFNVDBPUTPB-UHFFFAOYSA-N
InChI
1S/6CN.Fe.3K/c6*1-2;;;;/q;;;;;;-3;3*+1
SMILES string
[K+].[K+].[K+].N#C[Fe-3](C#N)(C#N)(C#N)(C#N)C#N
grade
ACS reagent, puriss. p.a.
agency
USP/NF, reag. ISO, reag. Ph. Eur.
assay
≥99%
form
crystalline
technique(s)
titration: suitable
impurities
≤0.02% hexacyanoferrate(II) ([Fe(CN)6]4-)
pH
6-9 (25 °C, 329 g/L)
anion traces
chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤50 mg/kg
cation traces
Ca: ≤5 mg/kg, Cd: ≤5 mg/kg, Co: ≤50 mg/kg, Cu: ≤10 mg/kg, Na: ≤200 mg/kg, Ni: ≤10 mg/kg, Pb: ≤20 mg/kg, Zn: ≤5 mg/kg
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General description
Potassium hexacyanoferrate(III) (Potassium ferricyanide) is an alkali hexacyanoferrate. On heating, it undergoes decomposition to afford yellow-brown hexacyanoiron(III) acid. It can be prepared by the anodic oxidation of K4[Fe(CN)6].
Application
Potassium hexacyanoferrate(III) may be employed as an oxidizing agent during the fabrication of glucose conductometric biosensor.
wgk
WGK 2
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Eye Irrit. 2
supp_hazards
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
Alemnew Geto et al.
Environment international, 129, 400-407 (2019-06-04)
Bentazone is one of the most problematic pesticides polluting groundwater resources. It is on the list of pesticides that are mandatory to analyze at water work controls. The current pesticide measuring approach includes manual water sampling and time-consuming chromatographical quantification
Eagleson M.
Concise Encyclopedia Chemistry, 291-291 (1994)
Glucose conductometric biosensor with potassium hexacyanoferrate (III) as an oxidizing agent.
Dzyadevich SV, et al.
Analytica Chimica Acta, 374(1), 11-18 (1998)
Liju Yang et al.
Biomedical microdevices, 13(2), 279-289 (2010-11-26)
Microlithographically fabricated interdigitated microsensor electrodes (IMEs) were cleaned, surface activated, chemically functionalized (amine) and derivatized with an Acrloyl-PEG-NHS to receive a spun-applied monomer cocktail of UV polymerizable monomer. IMEs were 2050.5, 1550.5, 1050.5 and 0550.5 possessing lines and spaces that
Lu Han et al.
Journal of pharmaceutical and biomedical analysis, 58, 141-145 (2011-10-15)
In this paper, a novel chemiluminescence (CL) system, 2-phenyl-4, 5-di (2-furyl) imidazole (PDFI)-potassium ferricyanide, for the determination of terbutaline sulfate was described. The method was based on enhancement of CL emission of PDFI-potassium ferricyanide system in the presence of terbutaline
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