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线性分子式:
CuSO4 · 5H2O
化学文摘社编号:
分子量:
249.69
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-847-6
MDL number:
Assay:
99-102%
Form:
solid
InChI key
JZCCFEFSEZPSOG-UHFFFAOYSA-L
InChI
1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
SMILES string
O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O
grade
ACS reagent, puriss. p.a.
agency
USP/NF, reag. ISO, reag. Ph. Eur.
vapor pressure
7.3 mmHg ( 25 °C)
assay
99-102%
form
solid
impurities
≤0.001% total nitrogen (N), ≤0.005% in water insoluble matters
pH
3.7-4.5 (20 °C, 5%)
mp
110 °C (dec.) (lit.)
anion traces
chloride (Cl-): ≤10 mg/kg
cation traces
As: ≤0.5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤10 mg/kg, Co: ≤10 mg/kg, Fe: ≤20 mg/kg, K: ≤10 mg/kg, Mg: ≤5 mg/kg, Na: ≤20 mg/kg, Ni: ≤20 mg/kg, Pb: ≤20 mg/kg, Zn: ≤300 mg/kg
Quality Level
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General description
五水硫酸铜(II)(CuSO4·5H2O,胆矾)是一种水合铜(II)盐。它能与三脚架配体发生水热反应,产生金属-有机骨架(MOF)。CuSO4·5H2O 与金属铜能够一起催化不同配体臂官能化偶氮酰胺的合成。当加热到560℃以上后,它会分解成CuO。
Application
五水硫酸铜(II)可用于以下研究:
- 在无溶剂条件下作为醇类和酚类乙酰化的催化剂。
- 制备用于Cu-Zn-Sn前体电沉积的电解质,它是制备Cu2ZnSnS4 (CZTS)薄膜所必需的。
- 作为乙醇的脱水反应的催化剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
Hangil Moon et al.
Materials (Basel, Switzerland), 13(5) (2020-03-11)
Despite the widespread application of activated carbon fiber (ACF) filters in air cleaning owing to their high surface area and low price, they have certain limitations in that they facilitate bacterial growth upon prolonged use as ACF filters can provide
Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
Preparation of Cu2ZnSnS4 thin films by sulfurization of co-electroplated Cu-Zn-Sn precursors.
Araki H, et al.
Physica Status Solidi, 6(5), 1266-1268 (2009)
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