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Merck
CN

33015

甲酸

greener alternative

puriss. p.a., ACS reagent, reag. Ph. Eur., ≥98%

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线性分子式:
HCOOH
化学文摘社编号:
分子量:
46.03
UNSPSC Code:
12352106
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-579-1
Beilstein/REAXYS Number:
1209246
MDL number:
Assay:
≥98%
Concentration:
≥98%
Form:
liquid
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InChI key

BDAGIHXWWSANSR-UHFFFAOYSA-N

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

SMILES string

OC=O

grade

ACS reagent, puriss. p.a.

agency

reag. Ph. Eur., suitable for EPA 1633

vapor density

1.6 (vs air)

vapor pressure

44.8 mmHg ( 20 °C)

assay

≥98%

form

liquid

autoignition temp.

1004 °F

expl. lim.

57 %

Quality Level

greener alternative product characteristics

Catalysis
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sustainability

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pH

2.2 (20 °C, 2.2 g/L)

bp

100-101 °C (lit.)

mp

8.2-8.4 °C (lit.)

solubility

water: miscible at 20 °C (in all proportions)

density

1.22 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤5 mg/kg, oxalate (C2O42-): ≤50 mg/kg, sulfate (SO42-): ≤5 mg/kg, sulfite (SO32-): ≤10 mg/kg

cation traces

Ag: ≤0.02 mg/kg, Al: ≤0.05 mg/kg, Ba: ≤0.05 mg/kg, Be: ≤0.02 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.2 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.05 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤2 mg/kg, Ge: ≤0.05 mg/kg, K: ≤0.1 mg/kg, Li: ≤0.02 mg/kg, Mg: ≤0.5 mg/kg, Mn: ≤0.05 mg/kg, Mo: ≤0.02 mg/kg, Na: ≤0.5 mg/kg, Ni: ≤0.05 mg/kg, Pb: ≤0.02 mg/kg, Sr: ≤0.02 mg/kg, Ti: ≤0.1 mg/kg, Tl: ≤0.05 mg/kg, V: ≤0.05 mg/kg, Zn: ≤0.05 mg/kg, Zr: ≤0.1 mg/kg

application(s)

PFAS testing

greener alternative category

concentration

≥98%

technique(s)

mass spectrometry (MS): suitable

impurities

≤0.001% ammonium (NH4), ≤0.001% non-volatile matter, ≤0.005% acetic acid (CH3COOH)

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General description

甲酸是一种简单的有机酸。甲酸基(-COOH)在组成复杂的生物分子(乙酸、甘氨酸、各种氨基酸)中起着重要作用。它具有较高极性,其偶极矩为1.41德拜。它已被报道作为聚合物电解质膜(PEM)燃料电池的替代燃料。其对Nafion 112和117膜的渗透性可与甲醇相媲美。
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

甲酸已被用于评估其第一个绝对差分弹性电子散射截面和角度差分截面(入射电子能量在1.8和50eV范围内)。它可用于制备用于质谱研究的HPLC缓冲液。

Other Notes

货号 33015-4X2.5L的产品即将停产。请订购33015-2.5L单瓶装,因为其具体参数与上述产品本质相同。
货号为33015-4X2.5L-M 的产品即将停产。请订购33015-2.5L-M单瓶装,因为其物理参数与上述产品本质相同。
货号33015-6X1L-M的产品即将停产。请订购33015-1L-M单瓶装,因为其物理参数与上述产品本质相同。

Legal Information

Nafion is a trademark of The Chemours Company FC, LLC

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

121.1 °F - closed cup

flash_point_c

49.5 °C - closed cup

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Crossover of formic acid through Nafion membranes.
Rhee Y-W, et al.
Journal of Power Sources, 117(1), 35-38 (2003)
Elastic electron scattering from formic acid (HCOOH): absolute differential cross-sections.
Vizcaino V, et al.
New Journal of Physics, 8(6), 85-85 (2006)
Heng Lu et al.
Cell communication insights, 5, 1-7 (2014-05-20)
Protein-protein interactions play a pivotal role in both inter- and intra-cellular signaling. Identification of signaling protein complexes can thus shed important new insights into cell communications. We developed a parallel affinity precipitation protocol to overcome the disadvantages of the tandem
Yoann Rombouts et al.
Annals of the rheumatic diseases, 74(1), 234-241 (2013-10-10)
To determine whether anticitrullinated protein antibodies (ACPA) exhibit specific changes in Fc glycosylation prior to the onset of arthritis. Serum samples of patients with ACPA-positive arthralgia (n=183) were collected at baseline and at various time points of follow-up. 105 patients
J Liesivuori et al.
Pharmacology & toxicology, 69(3), 157-163 (1991-09-01)
Metabolism of methanol, methyl ethers, esters and amides give rise to formic acid. This acid is an inhibitor of the mitochondrial cytochrome oxidase causing histotoxic hypoxia. Formic acid is a weaker inhibitor than cyanide and hydrosulphide anions. The body burden

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Glyphosate analysis: LC-MS/MS method with Supel™ Carbon LC U/HPLC column for stability and retention.

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