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Merck
CN

33120

N,N-二甲基甲酰胺

puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.8% (GC)

别名:

DMF, NSC 5356

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关于此项目

线性分子式:
HCON(CH3)2
化学文摘社编号:
分子量:
73.09
UNSPSC Code:
12352111
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-679-5
Beilstein/REAXYS Number:
605365
MDL number:
Assay:
≥99.8% (GC)
Technique(s):
GC/GC: suitable
Bp:
152-154 °C
153 °C (lit.)
Vapor pressure:
2.7 mmHg ( 20 °C)
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产品名称

N,N-二甲基甲酰胺, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.8% (GC)

InChI key

ZMXDDKWLCZADIW-UHFFFAOYSA-N

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

SMILES string

[H]C(=O)N(C)C

grade

ACS reagent
puriss. p.a.

agency

reag. Ph. Eur.

vapor density

2.5 (vs air)

vapor pressure

2.7 mmHg ( 20 °C)

assay

≥99.8% (GC)

form

liquid

autoignition temp.

833 °F

expl. lim.

15.2 %

technique(s)

GC/GC: suitable

impurities

≤0.003% free acid (as CH3COOH)
≤0.005% free alkali (as NH3)
≤0.005% non-volatile matter
≤0.1% water (Karl Fischer)

color

APHA: ≤15

refractive index

n20/D 1.4290-1.4310
n20/D 1.430 (lit.)

pH

7 (20 °C, 200 g/L)

bp

152-154 °C
153 °C (lit.)

mp

−61 °C (lit.)

density

0.948-0.950 g/mL at 20 °C
0.944 g/mL (lit.)

cation traces

Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≥0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤1 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sn: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Quality Level

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Application

N,N -二甲基甲酰胺 (DMF) 可用作以下研究的溶剂:
  • 黄瓜子叶完整组织中提取含叶绿素的色素。
  • 从单细胞海藻细胞培养物中分离叶绿素 a 。4
  • 作为还原剂和溶剂制备 Au@Ag 核壳纳米晶体。
多种疏水性有机化合物的溶剂。

General description

N,N -二甲基甲酰胺 (DMF) 通常用作各种有机反应的溶剂。DMF 是从植物组织中分离叶绿素的有效溶剂。它是有机合成中广泛使用的试剂。它在溶剂、脱水剂、还原剂、催化剂等多种反应中起作用。它是合成以 O,-CO,-NMe 2 ,-CONMe 2 ,-Me,-CHO 为官能团的化合物的多功能构件。

Other Notes

货号为33120-4X2.5L-M 的产品即将停产。请订购33120-2.5L-M单瓶装,因为其物理参数与上述产品本质相同。
货号33120-4X2.5L-R的产品即将停产。请订购33120-2.5L-R单瓶装,因为其具体参数与上述产品本质相同。
货号33120-6X1L-M的产品即将停产。请订购33120-1L-M单瓶装,因为其物理参数与上述产品本质相同。
货号33120-6X1L-R的产品即将停产。请订购33120-1L-R单瓶装,因为其具体参数与上述产品本质相同。

Packaging

PE瓶也有2.5 L

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

135.5 °F - closed cup

flash_point_c

57.5 °C - closed cup

法规信息

危险化学品
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分析证书(COA)

Lot/Batch Number

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R Moran et al.
Plant physiology, 65(3), 478-479 (1980-03-01)
Photosynthetic pigments from etiolated cucumber (Cucumis sativus var. Beit Alpha improved, Hazera Co., Gedera) cotyledons were extracted by direct immersion of the intact cotyledons into the solvent N,N-dimethylformamide (DMF). The solvent is especially efficient when pigment concentration is low; time
Shape-dependent evolution of Au@ Ag core- shell nanocrystals by PVP-assisted N,N-dimethylformamide reduction.
Tsuji M, et al.
Crystal Growth & Design, 8(7), 2528-2536 (2008)
W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined
Kun Liu et al.
Nanoscale, 4(20), 6574-6580 (2012-09-15)
Studies on the self-assembly of metal nanoparticles (NPs) in the presence of ions are motivated by the biosensing applications of NP clusters and the capability to control the morphology of clusters of oppositely charged NPs. The effect of ions has
L Piazza et al.
Nature communications, 6, 6407-6407 (2015-03-03)
Surface plasmon polaritons can confine electromagnetic fields in subwavelength spaces and are of interest for photonics, optical data storage devices and biosensing applications. In analogy to photons, they exhibit wave-particle duality, whose different aspects have recently been observed in separate

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