346136
二乙醚
≥99.0%, anhydrous, ACS reagent, contains BHT as inhibitor
别名:
乙醚, 醚
产品名称
二乙醚, ACS reagent, anhydrous, ≥99.0%, contains BHT as inhibitor
等级
ACS reagent
anhydrous
质量水平
蒸汽密度
2.6 (vs air)
蒸汽压
28.66 psi ( 55 °C)
8.56 psi ( 20 °C)
方案
≥99.0%
表单
liquid
自燃温度
320 °F
包含
BHT as inhibitor
expl. lim.
36.5 %
dilution
(for analytical testing)
杂质
Alcohol ( as CH3CH2OH ), passes test
≤0.0002 meq/g Titr. acid
≤0.001% Carbonyl ( as HCHO )
≤0.03% water
≤1 ppm Peroxide ( as H2O2)
蒸发残留物
≤0.001%
颜色
APHA: ≤10
折射率
n20/D 1.3530 (lit.)
沸点
34.6 °C (lit.)
mp
−116 °C (lit.)
密度
0.706 g/mL at 25 °C (lit.)
SMILES字符串
CCOCC
InChI
1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3
InChI key
RTZKZFJDLAIYFH-UHFFFAOYSA-N
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一般描述
Diethyl ether is a versatile organic solvent used in the fields of diesel engines, agriculture, food, chemical, biological, pharmaceutical, and medical industries.
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.
Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.
Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.
Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.
Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.
Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.
Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.
应用
Diethyl ether can be used as a solvent in the:
- Ring-opening polymerization of ε-caprolactone to synthesize polycaprolactone.
- Rh-catalyzed C-H allylation of amides with allyl halides to synthesize allylated amides.
- Photochemical α-bromination of aromatic and aliphatic carbonyl compounds with N-bromosuccinimide to synthesize α-brominated ketones.
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 1 - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-40.0 °F
闪点(°C)
-40 °C
法规信息
监管及禁止进口产品
Nema Hafezi et al.
Journal of the American Chemical Society, 134(30), 12861-12868 (2012-07-13)
A dynamic covalent library of interconverting imine constituents, dissolved in an acetonitrile/water mixture, undergoes constitutional reorganization upon phase separation induced by a physical stimulus (heat) or a chemical effector (inorganic salt, carbohydrate, organic solvent). The process has been made reversible
Alessandra Forni et al.
Journal of molecular graphics & modelling, 38, 31-39 (2012-10-23)
The solvent effect on the I⋯O halogen bonding in complexes of iodobenzene derivatives with formaldehyde has been investigated by systematically varying the substituents on the iodobenzene ring. Calculations have been performed at MP2 and DFT levels of theory, using the
Ether-directed ortho-C-H olefination with a palladium(II)/monoprotected amino acid catalyst.
Gang Li et al.
Angewandte Chemie (International ed. in English), 52(4), 1245-1247 (2012-12-15)
Tatsuya Yoshino et al.
Organic letters, 14(16), 4290-4292 (2012-08-09)
A highly efficient total synthesis of the 11-membered cyclic aspercyclides A (1) and B (2) has been achieved by chemo- and regioselective intramolecular oxidative C-O bond formation from differently substituted diphenols.
Faysal Benaskar et al.
ChemSusChem, 6(2), 353-366 (2012-11-30)
A μ(2)-process in the Ullmann-type C-O coupling of potassium phenolate and 4-chloropyridine was successfully performed in a combined microwave (MW) and microflow process. Selective MW absorption in a micro-fixed-bed reactor (μ-FBR) by using a supported Cu nanocatalyst resulted in an
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