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经验公式(希尔记法):
I2
化学文摘社编号:
分子量:
253.81
UNSPSC Code:
12141916
NACRES:
NA.21
PubChem Substance ID:
EC Number:
231-442-4
Beilstein/REAXYS Number:
3587194
MDL number:
Assay:
≥99%
Bp:
184 °C (lit.)
Vapor pressure:
0.31 mmHg ( 25 °C), 1 mmHg ( 38.7 °C)
InChI key
PNDPGZBMCMUPRI-UHFFFAOYSA-N
InChI
1S/I2/c1-2
vapor density
9 (vs air)
vapor pressure
0.31 mmHg ( 25 °C), 1 mmHg ( 38.7 °C)
product line
ReagentPlus®
assay
≥99%
form
flakes
resistivity
1.3E15 μΩ-cm
dilution
(for general lab use)
impurities
≤0.05% nonvolatile matter
bp
184 °C (lit.)
mp
113 °C (lit.)
Quality Level
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General description
Iodine is a micro nutrient essential for thyroid synthesis. It is a component of Gram′s iodine which has been reported to be used in identifying cellulase-producing microorganisms. Photogeneration of iodine from anatase TiO2 has been studied.
Application
Iodine may be used as a promoter during the synthesis of conjugated molecules with benzofulvene core. It may be employed as a TLC stain for detection of perillyl alcohol.
It may be used as a catalyst in the synthesis of the following:
It may be used as a catalyst in the synthesis of the following:
- Quinoxalines by reacting 1,2-diamines with 1,2-dicarbonyl compounds under microwave condition.
- N-Substituted pyrroles via condensation of 2,5-dimethoxy tetrahydrofuran with amines under microwave condition.
- Disulfidation of alkenes.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
target_organs
Respiratory system, Thyroid
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
Debasish Bandyopadhyay et al.
Molecules (Basel, Switzerland), 15(6), 4207-4212 (2010-07-27)
A microwave-induced iodine-catalyzed simple, rapid and convenient synthesis of different types of quinoxalines via condensation of 1,2-diamines with 1,2-dicarbonyl compounds has been accomplished with an excellent yield.
Farhana Ahad et al.
Indian journal of endocrinology and metabolism, 14(1), 13-17 (2010-01-01)
Iodine is a vital micronutrient required at all stages of life; fetal life and early childhood being the most critical phases of requirement. Diet is the sole source of iodine, which in turn is dependent upon the iodine content of
Iodine-catalyzed disulfidation of alkenes.
Wang XR and Chen F.
Tetrahedron, 67(25), 4547-4551 (2011)
Chockalingam Karunakaran et al.
Chemistry Central journal, 5(1), 31-31 (2011-06-18)
The crystal structures of different forms of TiO2 and those of BaTiO3, ZnO, SnO2, WO3, CuO, Fe2O3, Fe3O4, ZrO2 and Al2O3 nanoparticles have been deduced by powder X-ray diffraction. Their optical edges have been obtained by UV-visible diffuse reflectance spectra.
Processing cherries (Prunus avium) using supercritical fluid technology. Part 1: Recovery of extract fractions rich in bioactive compounds.
Serra AT, et al.
Journal of Supercritical Fluids, 55(1), 184-191 (2010)
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