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Merck
CN

376558

flakes, ReagentPlus®, ≥99%

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经验公式(希尔记法):
I2
化学文摘社编号:
分子量:
253.81
UNSPSC Code:
12141916
NACRES:
NA.21
PubChem Substance ID:
EC Number:
231-442-4
Beilstein/REAXYS Number:
3587194
MDL number:
Assay:
≥99%
Bp:
184 °C (lit.)
Vapor pressure:
0.31 mmHg ( 25 °C), 1 mmHg ( 38.7 °C)
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InChI key

PNDPGZBMCMUPRI-UHFFFAOYSA-N

InChI

1S/I2/c1-2

vapor density

9 (vs air)

vapor pressure

0.31 mmHg ( 25 °C), 1 mmHg ( 38.7 °C)

product line

ReagentPlus®

assay

≥99%

form

flakes

resistivity

1.3E15 μΩ-cm

dilution

(for general lab use)

impurities

≤0.05% nonvolatile matter

bp

184 °C (lit.)

mp

113 °C (lit.)

Quality Level

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General description

Iodine is a micro nutrient essential for thyroid synthesis. It is a component of Gram′s iodine which has been reported to be used in identifying cellulase-producing microorganisms. Photogeneration of iodine from anatase TiO2 has been studied.

Application

Iodine may be used as a promoter during the synthesis of conjugated molecules with benzofulvene core. It may be employed as a TLC stain for detection of perillyl alcohol.
It may be used as a catalyst in the synthesis of the following:
  • Quinoxalines by reacting 1,2-diamines with 1,2-dicarbonyl compounds under microwave condition.
  • N-Substituted pyrroles via condensation of 2,5-dimethoxy tetrahydrofuran with amines under microwave condition.
  • Disulfidation of alkenes.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

target_organs

Respiratory system, Thyroid

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Debasish Bandyopadhyay et al.
Molecules (Basel, Switzerland), 15(6), 4207-4212 (2010-07-27)
A microwave-induced iodine-catalyzed simple, rapid and convenient synthesis of different types of quinoxalines via condensation of 1,2-diamines with 1,2-dicarbonyl compounds has been accomplished with an excellent yield.
Farhana Ahad et al.
Indian journal of endocrinology and metabolism, 14(1), 13-17 (2010-01-01)
Iodine is a vital micronutrient required at all stages of life; fetal life and early childhood being the most critical phases of requirement. Diet is the sole source of iodine, which in turn is dependent upon the iodine content of
Iodine-catalyzed disulfidation of alkenes.
Wang XR and Chen F.
Tetrahedron, 67(25), 4547-4551 (2011)
Chockalingam Karunakaran et al.
Chemistry Central journal, 5(1), 31-31 (2011-06-18)
The crystal structures of different forms of TiO2 and those of BaTiO3, ZnO, SnO2, WO3, CuO, Fe2O3, Fe3O4, ZrO2 and Al2O3 nanoparticles have been deduced by powder X-ray diffraction. Their optical edges have been obtained by UV-visible diffuse reflectance spectra.
Processing cherries (Prunus avium) using supercritical fluid technology. Part 1: Recovery of extract fractions rich in bioactive compounds.
Serra AT, et al.
Journal of Supercritical Fluids, 55(1), 184-191 (2010)

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