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Merck
CN

435597

发烟硫酸

reagent grade, 20%, as free SO3

别名:

发烟硫酸

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关于此项目

线性分子式:
H2SO4 · (SO3)x
化学文摘社编号:
分子量:
98.08
UNSPSC Code:
12352106
NACRES:
NA.21
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2037554
Concentration:
20% (free SO3)
Form:
liquid
Grade:
reagent grade
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grade

reagent grade

Quality Segment

vapor density

3 (vs air)

vapor pressure

2 mmHg ( 25 °C)

form

liquid

concentration

20% (free SO3)

density

1.925 g/mL at 25 °C (lit.)

SMILES string

O=S(=O)=O.OS(O)(=O)=O

InChI

1S/H2O4S.O3S/c1-5(2,3)4;1-4(2)3/h(H2,1,2,3,4);

InChI key

HIFJUMGIHIZEPX-UHFFFAOYSA-N

General description

Fuming sulfuric acid is an inorganic acid, that can be produced by the addition of sulfur trioxide to concentrated sulfuric acid. It is commonly used as a sulfonating reagent in sulfonation reactions. When fuming sulfuric acid is employed as reaction medium, bromination takes place only in the pyridine nucleus of isomeric methylpyridines and 2,6-dimethylpyridine. It can also oxidize fullerene C60 to form fullerene polymers.

Application

Fuming sulfuric acid may be used as a sulfonating agent for the synthesis of:
  • sulfonated poly(1,4-phenylene sulfide)
  • water-soluble polyphosphazene polyelectrolyte
  • sulfated graphene


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pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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