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Merck
CN

44939

氯化亚铁 四水合物

puriss. p.a., ≥99.0% (RT)

别名:

氯化亚铁 四水合物

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关于此项目

线性分子式:
FeCl2 · 4H2O
化学文摘社编号:
分子量:
198.81
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-843-4
MDL number:
Assay:
≥99.0% (RT)
Form:
powder or crystals
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产品名称

氯化亚铁 四水合物, puriss. p.a., ≥99.0% (RT)

InChI key

WSSMOXHYUFMBLS-UHFFFAOYSA-L

InChI

1S/2ClH.Fe.4H2O/h2*1H;;4*1H2/q;;+2;;;;/p-2

SMILES string

O.O.O.O.Cl[Fe]Cl

vapor pressure

10 mmHg ( 693 °C)

grade

puriss. p.a.

assay

≥99.0% (RT)

form

powder or crystals

impurities

≤0.001% total nitrogen (N)

pH

2.5 (20 °C, 100 g/L)

anion traces

sulfate (SO42-): ≤100 mg/kg

cation traces

As: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤50 mg/kg
Cr: ≤10 mg/kg
Cu: ≤5 mg/kg
Fe3+: ≤2000 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤50 mg/kg
Na: ≤50 mg/kg
Ni: ≤50 mg/kg
Pb: ≤10 mg/kg
Zn: ≤20 mg/kg

Quality Level

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Application

氯化铁(II)四水合物可以作为催化剂用于:
  • 腈和各种卤代烃合成 N-取代酰胺的无溶剂Ritter反应。
  • 炔间接水化反应合成酮。
  • 在锂和DTBB的参与下立体选择性地将 α, β-不饱和羰基化合物还原成相应的饱和醇。
它也可以用作制备铁-双膦配合物的前体,该配合物可以用于催化Kumada­-Tamao-­Corriu偶联。

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

存储类别

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

does not flash

flash_point_c

does not flash


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Maren Depke et al.
Cytometry. Part A : the journal of the International Society for Analytical Cytology, 85(2), 140-150 (2013-12-19)
Throughout the world, infections caused by bacteria such as Staphylococcus aureus are a major cause of morbidity and mortality. In order to gain some understanding of the complicated physiological link between host and pathogen, modern techniques such as confocal microscopy
Hui Wei et al.
Molecules (Basel, Switzerland), 25(6) (2020-04-05)
Ferrous ion co-catalyst enhancement of dilute-acid (DA) pretreatment of biomass is a promising technology for increasing the release of sugars from recalcitrant lignocellulosic biomass. However, due to the reductive status of ferrous ion and its susceptibility to oxidation with exposure
Electron microscopy study of CVT grown Fe-sulphides.
Zavasnik J and Recnik A.
Journal of Crystal Growth, 367, 18-23 (2013)
Chenglong Yuan et al.
International journal of molecular sciences, 20(3) (2019-02-13)
The prion protein (PrPSc) has drawn widespread attention due to its pathological potential to cause prion diseases. Herein, we successfully synthesized Fe₃C@C by carbonizing Fe₃O₄-lignin clusters, which were prepared through a facile hydrogen bonding interaction between ≡Fe-OH and hydroxyl groups
The crystal structure of iron (II) chloride tetrahydrate.
Penfold BR and Grigor JA.
Acta Crystallographica, 12(11), 850854-850854 (1959)

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