537705
5-甲基-2-己酮
99%
别名:
MIAK, 异丁基丙酮, 异戊基甲基酮
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关于此项目
线性分子式:
(CH3)2CHCH2CH2COCH3
化学文摘社编号:
分子量:
114.19
UNSPSC Code:
12352115
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-737-8
Beilstein/REAXYS Number:
506163
MDL number:
Assay:
99%
Bp:
145 °C (lit.)
Vapor pressure:
4.5 mmHg ( 20 °C)
vapor density
3.94 (vs air)
Quality Segment
vapor pressure
4.5 mmHg ( 20 °C)
assay
99%
autoignition temp.
797 °F
expl. lim.
1.35-8.2 %, 93 °F
impurities
≤0.05% (water)
refractive index
n20/D 1.406 (lit.)
bp
145 °C (lit.)
mp
-74 °C
solubility
water: soluble 5.4 g/L at 25 °C
density
0.814 g/mL at 25 °C (lit.)
SMILES string
CC(C)CCC(C)=O
InChI
1S/C7H14O/c1-6(2)4-5-7(3)8/h6H,4-5H2,1-3H3
InChI key
FFWSICBKRCICMR-UHFFFAOYSA-N
General description
5-Methyl-2-hexanone (methyl isoamyl ketone, MIAK) is an aliphatic ketone. Its ability to elicit germination response in uredospores of certain species of rust has been investigated. The near-UV absorption cross section and absorption spectrum of MIAK were measured and employed to determine its photolysis lifetime. The dynamics of the Norrish Type-II reaction of MIAK has been studied using femtosecond time-resolved mass spectrometry.
Application
5-Methyl-2-hexanone may be used to synthesize N,N′-bis(1,4-dimethylpentyl)-p-phenylenediamine (BMPPD) via reductive alkylation of p-nitroaniline in the presence of copper-based catalysts.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
104.0 °F - closed cup
flash_point_c
40 °C - closed cup