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Merck
CN

63102

Sigma-Aldrich

高氯酸镁

puriss., free-flowing powder, ≥99.0% (calc. based on dry substance, KT)

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关于此项目

线性分子式:
Mg(ClO4)2
CAS Number:
分子量:
223.21
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
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等级

puriss.

质量水平

方案

≥99.0% (calc. based on dry substance, KT)

表单

free flowing powder

质量

free-flowing powder

杂质

≤8% water

储存温度

room temp

SMILES字符串

[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2

InChI key

MPCRDALPQLDDFX-UHFFFAOYSA-L

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一般描述

Magnesium perchlorate (Mg(ClO4)2) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.

应用

干燥管的填充剂(尤其是用于元素分析)
Magnesium perchlorate (Mg(ClO4)2) may be employed as a catalyst in the following studies:
  • Preparation of a-aminophosphonates.
  • Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.
  • Preparation of imines and phenylhydrazones.
  • Protection of alcohols in the form of t-butyl ethers.

象形图

Flame over circleExclamation mark

警示用语:

Danger

危险分类

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Giuseppe Bartoli et al.
Organic letters, 7(3), 427-430 (2005-01-28)
[reaction: see text] A new mild method for protecting alcohols as t-butyl ethers is reported. The reaction proceeds with Mg(ClO4)2 and Boc2O and shows general applicability. The deprotection of t-butyl ethers has also been revisited. Preliminary results indicate the CeCl3
Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones.
Chakraborti AK, et al.
Tetrahedron Letters, 45(41), 7641-7644 (2004)
Eagleson M.
Concise Encyclopedia Chemistry, 343-343 (1994)
The first enantioselective synthesis of both Diels-Alder enantiomers with the same bis (oxazoline)-magnesium perchlorate chiral catalyst.
Desimoni G, et al.
Tetrahedron Letters, 37(17), 3027-3030 (1996)
J D Anastassopoulou et al.
Magnesium research, 3(1), 15-18 (1990-03-01)
This study examined the effects on the radiolysis of magnesium-guanosine-5'-monophosphate complexes in deaerated aqueous solutions, investigated by Fourier transform infrared (FT-IR) spectroscopy. It was found that when the system was irradiated with a dose rate of 500 rad/min (low dose

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