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Merck
CN

676934

1,4-二氧六环

ACS reagent, ≥99.0%, contains <=25 ppm BHT as stabilizer

别名:

二恶烷, 四氢呋喃

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关于此项目

经验公式(希尔记法):
C4H8O2
化学文摘社编号:
分子量:
88.11
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-661-8
Beilstein/REAXYS Number:
102551
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Technique(s):
thin layer chromatography (TLC): suitable
Bp:
100-102 °C (lit.)
Vapor pressure:
27 mmHg ( 20 °C), 40 mmHg ( 25 °C)
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grade

ACS reagent

Quality Level

vapor density

3 (vs air)

vapor pressure

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

assay

≥99.0%

form

liquid

autoignition temp.

356 °F

expl. lim.

22 %

technique(s)

thin layer chromatography (TLC): suitable

impurities

≤0.0016 meq/g Titr. acid, ≤0.005% Peroxide as (H2O2), ≤0.01% Carbonyl (as HCHO), ≤0.05% water

evapn. residue

≤0.005%

color

APHA: ≤20

refractive index

n20/D 1.422 (lit.)

pH

6.0-8 (20 °C, 500 g/L)

bp

100-102 °C (lit.)

mp

10-12 °C (lit.)

transition temp

freezing point ≥11.0

density

1.034 g/mL at 25 °C (lit.)

SMILES string

C1COCCO1

InChI

1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2

InChI key

RYHBNJHYFVUHQT-UHFFFAOYSA-N

General description

1,4-二恶烷被广泛用作工业中各种有机化合物的溶剂。它是在工业废水中发现的一种不可生物降解的污染物。它通过使用氧气和臭氧而进行的氧化降解,有助于将其转化为可生物降解的产物,并可通过常规方法轻松去除。
Our premium ACS solvents are ideal for routine chemical synthesis, drying, purification, and critical labware cleaning. They meet or exceed the rigorous standards of the American Chemical Society (ACS), ensuring high-quality results for your research needs.

Premium ACS Solvents: Our solvents meet or exceed the stringent standards set by the American Chemical Society, ensuring high quality and reliability for your laboratory applications.

Replicable and Publishable Results: Designed for consistency, our solvents deliver results that can be reliably reproduced, making them ideal for research that requires publication.

Versatile Applications: Suitable for routine chemical synthesis, drying, purification, and critical labware cleaning, our solvents cater to a wide range of research needs in the laboratory.

Application

1,4-二恶烷可用作N-(4-(丙-2-炔基氧基)苯基)乙酰胺和3-(4-(丙-2-炔氧基)苯基)-3,4-二氢-2H-苯并[e][1,3]恶嗪合成中的溶剂。


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signalword

Danger

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

法规信息

危险化学品

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分析证书(COA)

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Oxidation and biodegradability enhancement of 1,4-dioxane using hydrogen peroxide and ozone.
C D Adams et al.
Environmental science & technology, 28(11), 1812-1818 (1994-10-01)
Self-curable benzoxazine functional polybutadienes synthesized by click chemistry.
Kukut M, et al.
Designed Monomers and Polymers, 12(2), 167-176 (2009)
Christof Aellig et al.
ChemSusChem, 5(9), 1737-1742 (2012-07-05)
The dehydration of D-fructose to 5-hydroxymethylfurfural was studied under single-phase conditions in the low boiling solvent 1,4-dioxane at moderate temperatures in the presence of the solid acid-catalyst Amberlyst-15. The reaction was first examined and optimized under batch conditions, where it



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货号GTIN
676934-1L04061832748283
676934-4L04061832748290