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关于此项目
线性分子式:
Na3Co(NO2)6
化学文摘社编号:
分子量:
403.94
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
237-077-7
MDL number:
Form:
powder
Quality Level
grade
ACS reagent, puriss. p.a.
form
powder
quality
for the determination of K
mp
220 °C (dec.) (lit.)
anion traces
chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤500 mg/kg
cation traces
Ca: ≤50 mg/kg, Cd: ≤5 mg/kg, Cr: ≤50 mg/kg, Cu: ≤5 mg/kg, Fe: ≤20 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Ni: ≤20 mg/kg, Pb: ≤100 mg/kg, Zn: ≤10 mg/kg
suitability
in accordance for determination of potassium
SMILES string
[Na+].[Na+].[Na+].[O-][N+](=O)[Co-3]([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O
InChI
1S/Co.6NO2.3Na/c;6*2-1-3;;;/q-3;;;;;;;3*+1
InChI key
IMBXIBFCGMYSME-UHFFFAOYSA-N
Application
Sodium hexanitrocobaltate(III) (Na3Co(NO2)6) may be employed as a nitrosation reagent for various amino group containing organic compounds (aliphatic and aromatic).
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signalword
Danger
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Ox. Sol. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
5.1B - Oxidizing hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
The thermal dissociation of sodium hexanitrocobaltate (III).
Wendlandt W and Southern T.
Journal of Thermal Analysis and Calorimetry, 2(1), 87-89 (1970)
[Hygienic standard basis for potassium hexanitrocobaltate in the water of reservoirs].
A A Korolev
Gigiena i sanitariia, (10)(10), 72-73 (1980-10-01)
Bogdan Stefane et al.
The Journal of organic chemistry, 62(21), 7165-7169 (2001-10-24)
Na(3)Co(NO(2))(6) has been investigated as a new reagent for the nitrosation of various substrates containing an amino functionality. Reactions took place in an aqueous solution of the reagent. The pH of the reaction mixture remained in the range 4.3-5. Thus
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